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HomeProduct name listDIBENZYL DIETHYLPHOSPHORAMIDITE

DIBENZYL DIETHYLPHOSPHORAMIDITE

Synonym(s):TTC

DIBENZYL DIETHYLPHOSPHORAMIDITE Structural

What is DIBENZYL DIETHYLPHOSPHORAMIDITE?

Chemical properties

Clear Colourless Liquid

The Uses of DIBENZYL DIETHYLPHOSPHORAMIDITE

Dibenzyl diethylphosphoramidite is a useful reagent for the efficient phosphorylative conversion of alcohols into their corresponding dibenzylphosphorotriesters as well as dibenzyl glycosyl phosphites, which can easily be converted to glycosyl phosphates or used in glycosylation reagents in oligosaccharide synthesis.

The Uses of DIBENZYL DIETHYLPHOSPHORAMIDITE

Dibenzyl N,N-diethylphosphoramidite may be used:

  • as phosphitylating reagent in the synthesis of glycosyl phosphites and phosphates
  • for phosphorylating the alcohols
  • in the preparation of 6-dibenzylphosphate-1,3,5-tri-O-PMB-myo-inositol

General Description

Dibenzyl N,N-diethylphosphoramidite is repoted to be suitable reagent for the efficient 1H-tetrazole-catalyzed ′phosphite-triester′ phosphorylation of the protected serine derivatives.

Properties of DIBENZYL DIETHYLPHOSPHORAMIDITE

Boiling point: 131-132 °C(Press: 0.0001 Torr)
Density  1.06 g/mL at 25 °C(lit.)
vapor pressure  0.71 psi ( 55 °C)
refractive index  n20/D 1.545(lit.)
Flash point: 95 °F
storage temp.  2-8°C
solubility  Soluble in chloroform.
pka 4.01±0.70(Predicted)
form  Oil
color  Clear Colourless to Pale Yellow
Sensitive  Moisture Sensitive
BRN  4189915
Stability: Light Sensitive
CAS DataBase Reference 67746-43-4

Safety information for DIBENZYL DIETHYLPHOSPHORAMIDITE

Signal word Warning
Pictogram(s)
ghs
Flame
Flammables
GHS02
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H226:Flammable liquids
H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for DIBENZYL DIETHYLPHOSPHORAMIDITE

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