Diaminomaleonitrile

Synonym(s):DAMN

CAS NO.：1187-42-4
Empirical Formula: C4H4N4
Molecular Weight: 108.1
MDL number: MFCD00001870
EINECS: 214-697-6
SAFETY DATA SHEET (SDS)
Update Date: 2024-11-04 20:04:50

What is Diaminomaleonitrile?

Chemical properties

brown crystalline powder

The Uses of Diaminomaleonitrile

Diaminomaleonitrile is a reagent used for the synthesis of 1,4-diazepine-2,3-dicarbonitrile dervatives. Also, it is used for the synthesis of Diaminomaleonitrile-based Schiff bases with a donor-acceptor structure and an aggregation-enhanced emission feature.

Preparation

Diaminomaleonitrile is obtained by tetramerization of hydrocyanic acid in the presence of catalysts such as alkylaluminum compounds.

Synthesis Reference(s)

The Journal of Organic Chemistry, 37, p. 4133, 1972 DOI: 10.1021/jo00798a037

General Description

Brown powder.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Diaminomaleonitrile is sensitive to prolonged exposure to air.

Fire Hazard

Flash point data are not available for Diaminomaleonitrile, but Diaminomaleonitrile is probably combustible.

Solubility in organics

They are soluble in methanol, ethanol, and N,N-dimethylformamide; slightly soluble in water and dioxane; and insoluble in acetone, benzene, xylene, and carbon disulfifide.

Properties of Diaminomaleonitrile

Melting point:	178-179 °C (lit.)
Boiling point:	192.71°C (rough estimate)
Density	1,36 g/cm³
refractive index	1.6260 (estimate)
storage temp.	Keep in dark place,Sealed in dry,Room Temperature
solubility	5000mg/l
form	Crystalline Powder
pka	-2.77±0.70(Predicted)
color	Brown
Water Solubility	5 g/L (25 ºC)
Sensitive	Light Sensitive
BRN	878333
Exposure limits	NIOSH: IDLH 25 mg/m3
CAS DataBase Reference	1187-42-4(CAS DataBase Reference)
EPA Substance Registry System	Diaminomaleonitrile (1187-42-4)

Safety information for Diaminomaleonitrile

Signal word	Warning
Pictogram(s)	Exclamation Mark Irritant GHS07
Precautionary Statement Codes	P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P280:Wear protective gloves/protective clothing/eye protection/face protection. P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.