Diaminomaleonitrile
Synonym(s):DAMN
- CAS NO.：1187-42-4
- Empirical Formula: C4H4N4
- Molecular Weight: 108.1
- MDL number: MFCD00001870
- EINECS: 214-697-6
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-12-18 14:15:30
What is Diaminomaleonitrile?
Chemical properties
brown crystalline powder
The Uses of Diaminomaleonitrile
Diaminomaleonitrile is a reagent used for the synthesis of 1,4-diazepine-2,3-dicarbonitrile dervatives. Also, it is used for the synthesis of Diaminomaleonitrile-based Schiff bases with a donor-acceptor structure and an aggregation-enhanced emission feature.
Preparation
Diaminomaleonitrile is obtained by tetramerization of hydrocyanic acid in the presence of catalysts such as alkylaluminum compounds.
Synthesis Reference(s)
The Journal of Organic Chemistry, 37, p. 4133, 1972 DOI: 10.1021/jo00798a037
General Description
Brown powder.
Air & Water Reactions
Insoluble in water.
Reactivity Profile
Diaminomaleonitrile is sensitive to prolonged exposure to air.
Fire Hazard
Flash point data are not available for Diaminomaleonitrile, but Diaminomaleonitrile is probably combustible.
Solubility in organics
They are soluble in methanol, ethanol, and N,N-dimethylformamide; slightly soluble in water and dioxane; and insoluble in acetone, benzene, xylene, and carbon disulfifide.
Properties of Diaminomaleonitrile
| Melting point: | 178-179 °C (lit.) |
| Boiling point: | 192.71°C (rough estimate) |
| Density | 1,36 g/cm3 |
| refractive index | 1.6260 (estimate) |
| storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
| solubility | 5000mg/l |
| form | Crystalline Powder |
| pka | -2.77±0.70(Predicted) |
| color | Brown |
| Water Solubility | 5 g/L (25 ºC) |
| Sensitive | Light Sensitive |
| BRN | 878333 |
| Exposure limits | NIOSH: IDLH 25 mg/m3 |
| CAS DataBase Reference | 1187-42-4(CAS DataBase Reference) |
| EPA Substance Registry System | Diaminomaleonitrile (1187-42-4) |
Safety information for Diaminomaleonitrile
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P280:Wear protective gloves/protective clothing/eye protection/face protection. P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. |
Computed Descriptors for Diaminomaleonitrile
New Products
(S)-3-Aminobutanenitrile hydrochloride 4-Methylphenylacetic acid N-Boc-D-alaninol N-BOC-D/L-ALANINOL Tert-butyl bis(2-chloroethyl)carbamate 3-Morpholino-1-(4-nitrophenyl)-5,6-dihydropyridin- 2(1H)-one Furan-2,5-Dicarboxylic Acid Tropic acid 1-Bromo-3,5-Di-Tert-Butylbenzene S-2-CHLORO PROPIONIC ACID ETHYL ISOCYANOACETATE 2-Bromo-1,3-Bis(Dimethylamino)Trimethinium Hexafluorophosphate 4-IODO BENZOIC ACID 3-NITRO-2-METHYL ANILINE 1-(2,4-DICHLOROPHENYL) ETHANAMINE (2-Hydroxyphenyl)acetonitrile 4-Bromopyrazole 2-(Cyanocyclohexyl)acetic acid 4-methoxy-3,5-dinitropyridine 1-(4-(aminomethyl)benzyl)urea hydrochloride 2-aminopropyl benzoate hydrochloride diethyl 2-(2-((tertbutoxycarbonyl)amino) ethyl)malonate tert-butyl 4- (ureidomethyl)benzylcarbamate Ethyl-2-chloro((4-methoxyphenyl)hydrazono)acetateRelated products of tetrahydrofuran
![2-AMINO-3-([(2,4-DICHLORO-1,3-THIAZOL-5-YL)METHYL]AMINO)BUT-2-ENEDINITRILE](https://img.chemicalbook.in/StructureFile/ChemBookStructure2/GIF/CB8398273.gif)
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