Di-tert-butylchlorophosphane
- CAS NO.：13716-10-4
- Empirical Formula: C8H18ClP
- Molecular Weight: 180.66
- MDL number: MFCD00008815
- EINECS: 237-266-4
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-12-21 17:48:05
What is Di-tert-butylchlorophosphane?
Chemical properties
Colorless to light yellow liqui
The Uses of Di-tert-butylchlorophosphane
Di-tert-butylchlorophosphine is associated with palladium(II) acetate and used in Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides. It serves as a ligand and used in the preparation of mono- and bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations. Further, it is used in asymmetric and transition metal coupling reactions. In addition to this, it plays an important role in the preparation of other phosphines in catalytic polymerization reactions.
The Uses of Di-tert-butylchlorophosphane
Di-tert-butylchlorophosphine is used as a catalyst in organic synthesis.
The Uses of Di-tert-butylchlorophosphane
Bulky ligand used with Pd(OAc)2 in efficient Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides.
What are the applications of Application
Bulky ligand used with Pd(OAc)2 in efficient Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides.
Precautions
Air and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents and strong reducing agents.
Properties of Di-tert-butylchlorophosphane
| Melting point: | 2-3°C |
| Boiling point: | 48 °C/3 mmHg (lit.) |
| Density | 0.951 g/mL at 25 °C (lit.) |
| refractive index | n |
| Flash point: | 142 °F |
| solubility | Miscible with terahydrofuran. |
| form | Liquid |
| color | Clear colorless |
| Specific Gravity | 0.951 |
| Sensitive | Air & Moisture Sensitive |
| CAS DataBase Reference | 13716-10-4(CAS DataBase Reference) |
| NIST Chemistry Reference | Phosphinous chloride, bis(1,1-dimethylethyl)-(13716-10-4) |
Safety information for Di-tert-butylchlorophosphane
| Signal word | Danger |
| Pictogram(s) |
 Corrosion Corrosives GHS05 |
| GHS Hazard Statements |
H314:Skin corrosion/irritation |
| Precautionary Statement Codes |
P280:Wear protective gloves/protective clothing/eye protection/face protection. P363:Wash contaminated clothing before reuse. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P405:Store locked up. |
Computed Descriptors for Di-tert-butylchlorophosphane
| InChIKey | MCRSZLVSRGTMIH-UHFFFAOYSA-N |
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