Cylopropylmethyl chloride
- CAS NO.：5911-08-0
- Empirical Formula: C4H7Cl
- Molecular Weight: 90.55
- MDL number: MFCD00001307
- EINECS: 227-632-1
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-12-10 11:57:34
What is Cylopropylmethyl chloride?
Chemical properties
Colorless to pale yellow liquid
The Uses of Cylopropylmethyl chloride
(Chloromethyl)cyclopropane was used in the synthesis of (lithiomethyl)cyclopropane and homoallyllithium via 4,4?-di-tert-butylbiphenyl or naphthalene-catalysed lithiation reaction. On reaction with isolable dialkylsilylene affords 5-silaspiro[4.4]nonane derivative.
The Uses of Cylopropylmethyl chloride
(Chloromethyl)cyclopropane was used in the synthesis of (lithiomethyl)cyclopropane and homoallyllithium via 4,4′-di-tert-butylbiphenyl or naphthalene-catalysed lithiation reaction.
Synthesis Reference(s)
Tetrahedron Letters, 13, p. 2135, 1972 DOI: 10.1016/S0040-4039(01)84787-0
General Description
(Chloromethyl)cyclopropane on reaction with isolable dialkylsilylene affords 5-silaspiro[4.4]nonane derivative.
Properties of Cylopropylmethyl chloride
| Melting point: | -91°C |
| Boiling point: | 87-89 °C(lit.) |
| Density | 0.98 g/mL at 25 °C(lit.) |
| refractive index | n |
| Flash point: | 29 °F |
| storage temp. | Inert atmosphere,2-8°C |
| solubility | soluble in Chloroform, Methanol |
| form | clear liquid |
| color | Colorless to Almost colorless |
| Water Solubility | Not miscible in water. |
| BRN | 635697 |
| CAS DataBase Reference | 5911-08-0(CAS DataBase Reference) |
| NIST Chemistry Reference | (Chloromethyl)cyclopropane(5911-08-0) |
Safety information for Cylopropylmethyl chloride
| Signal word | Danger |
| Pictogram(s) |
 Flame Flammables GHS02  Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H225:Flammable liquids H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for Cylopropylmethyl chloride
| InChIKey | ZVTQWXCKQTUVPY-UHFFFAOYSA-N |
Cylopropylmethyl chloride manufacturer
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