cyclopropanol
- CAS NO.:16545-68-9
- Empirical Formula: C3H6O
- Molecular Weight: 58.08
- MDL number: MFCD19707103
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-01-08 11:28:09
What is cyclopropanol?
Description
Cyclopropanols can be readily synthesized via synthetic transformations such as the Kulinkovich cyclopropanation and the Simmons-Smith reaction [1]. Due to the high strains built intrinsically in the three-membered ring, cyclopropanols and their derivatives are highly reactive and can undergo various ring opening/expansion/fragmentation reactions. A significant amount of these ring opening/expansion/fragmentation reactions are catalyzed/promoted by transition metal complexes. In many of these cases, cyclopropanols and their derivatives are considered as the equivalents of homoenolates or β-alkyl radicals.
The Uses of cyclopropanol
Cyclopropanol is a basic building block.
Definition
ChEBI: Cyclopropanol is a cyclopropane in which a hydrogen atom is replaced by a hydroxy group. It is a member of cyclopropanes and an aliphatic alcohol.
References
[1] Xinpei Cai, Mingji Dai, Weida Liang. “Total syntheses via cyclopropanols.” Tetrahedron 75 2 (2019): Pages 193-208.
Properties of cyclopropanol
Melting point: | 180℃ |
Boiling point: | 101-102℃ (760 Torr) |
Density | 9.9110 g/cm3 |
refractive index | 1.4129 (589.3 nm 20℃) |
storage temp. | 2-8°C |
pka | 15.31±0.20(Predicted) |
InChI | InChI=1S/C3H6O/c4-3-1-2-3/h3-4H,1-2H2 |
Safety information for cyclopropanol
Computed Descriptors for cyclopropanol
InChIKey | YOXHCYXIAVIFCZ-UHFFFAOYSA-N |
SMILES | C1(O)CC1 |
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