CYCLOOCTENE OXIDE
Synonym(s):9-Oxabicyclo[6.1.0]nonane;Epoxycyclooctane
- CAS NO.:286-62-4
- Empirical Formula: C8H14O
- Molecular Weight: 126.2
- MDL number: MFCD00005164
- EINECS: 206-010-3
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-04-23 13:52:06
What is CYCLOOCTENE OXIDE?
Chemical properties
COLOURLESS TO WHITE ADHERING CRYSTALS OR CHUNKS
Synthesis Reference(s)
The Journal of Organic Chemistry, 43, p. 1689, 1978 DOI: 10.1021/jo00403a015
Tetrahedron Letters, 27, p. 2617, 1986 DOI: 10.1016/S0040-4039(00)84599-2
Purification Methods
It can be distilled in vacuum, and the solidified distillate can be sublimed in vacuum below 50o. It has a characteristic odour. [IR: Cope et al. J Am Chem Soc 74 5884 1952, cf trans-isomer: Cope et al. J Am Chem Soc 79 3905 1957, Reppe et al. Justus Liebigs Ann Chem 560 1 1948].
Properties of CYCLOOCTENE OXIDE
Melting point: | 53-56 °C(lit.) |
Boiling point: | 55 °C5 mm Hg(lit.) |
Density | 0.9090 (rough estimate) |
refractive index | 1.4540 (estimate) |
Flash point: | 133 °F |
storage temp. | 2-8°C |
solubility | soluble in Methanol |
form | powder to crystal |
color | White to Almost white |
BRN | 103543 |
CAS DataBase Reference | 286-62-4(CAS DataBase Reference) |
Safety information for CYCLOOCTENE OXIDE
Signal word | Danger |
Pictogram(s) |
Flame Flammables GHS02 Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H228:Flammable solids H302:Acute toxicity,oral H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation |
Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for CYCLOOCTENE OXIDE
Related products of tetrahydrofuran
HEPTACHLOR EPOXIDE (ISOMER B) (13C1)
1,2,5,6-DIEPOXYCYCLOOCTANE
OXY-CHLORDENE
(+)-OXY-CHLORDANE
coriolin
CYCLOOCTENE OXIDE
CRINIPELLIN A
DICYCLOPENTADIENE DIOXIDE, ENDO
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