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HomeProduct name listCYCLOHEXYLZINC BROMIDE

CYCLOHEXYLZINC BROMIDE

CYCLOHEXYLZINC BROMIDE Structural

What is CYCLOHEXYLZINC BROMIDE?

The Uses of CYCLOHEXYLZINC BROMIDE

Cyclohexylzinc bromide is an organozinc reagent, generally used in Negishi coupling. Examples include the cross-coupling of alkylzinc halides with aryl/heteroaryl halides using Pd-PEPPSI-IPent and nickel-catalyzed synthesis of 4-substituted coumarins.

It can react with the SO2 surrogate, 1,4-diazabicyclo[2.2.2]octane bis(sulfur dioxide) adduct (DABSO) to afford zinc sulfinate salts which can be alkylated to synthesize various useful sulfones.

The Uses of CYCLOHEXYLZINC BROMIDE

It is used as primary and secondary intermediate.

Properties of CYCLOHEXYLZINC BROMIDE

Melting point: 114.0-116.0 °C
Density  0.963 g/mL at 25 °C
Flash point: 3 °F
storage temp.  2-8°C
Water Solubility  Reacts with water.
Sensitive  Air Sensitive
Exposure limits ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)

Safety information for CYCLOHEXYLZINC BROMIDE

Signal word Danger
Pictogram(s)
ghs
Flame
Flammables
GHS02
ghs
Corrosion
Corrosives
GHS05
ghs
Exclamation Mark
Irritant
GHS07
ghs
Health Hazard
GHS08
GHS Hazard Statements H225:Flammable liquids
H250:Pyrophoric liquids; Pyrorophoric solids
H261:Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases
H302:Acute toxicity,oral
H314:Skin corrosion/irritation
H318:Serious eye damage/eye irritation
H333:Acute toxicity,inhalation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
H351:Carcinogenicity
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P223:Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P231:Handle under inert gas.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378:In case of fire: Use … for extinction.
P405:Store locked up.
P422:Store contents under …

Computed Descriptors for CYCLOHEXYLZINC BROMIDE

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