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HomeProduct name listCupric carbonate basic

Cupric carbonate basic

Synonym(s):Cupric carbonate basic

  • CAS NO.:12069-69-1
  • Empirical Formula: CO3.Cu.CuH2O2
  • Molecular Weight: 221.11
  • MDL number: MFCD00010976
  • EINECS: 235-113-6
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-10-25 16:21:11
Cupric carbonate basic Structural

What is Cupric carbonate basic?

Chemical properties

Copper carbonate (basic), dark green monoclinic crystals, insoluble in cold H20, decomposes in H20, soluble in potassium cyanide. Malachite, copper ore, is of this composition. Refmed compound is used as a pigment.

Chemical properties

Copper Carbonate (Basic), CuCO3·Cu(OH)2, darkgreen monoclinic crystals, insoluble in cold H2O decomposes in hot H2O, soluble in potassium cyanide. Malachite, a copper ore, is of this composition. Refined compound is used as a pigment.

Physical properties

Natural malachite is a dark green crystalline solid; monoclinic crystals; density 4.0 g/cm3; refractive index 1.655; decomposes at 200°C; insoluble in cold water and alcohols; decomposes in hot water; soluble in acids, ammonium hydroxide and potassium cyanide solutions. Natural azurite is blue monoclinic crystal; density 3.88 g/cm3shiz; refractive index 1.730; decomposes at 220°C; insoluble in cold water; decomposes in hot water; soluble in ammonium hydroxide and hot sodium bicarbonate solutions.

The Uses of Cupric carbonate basic

Used to kill algae and as a pigment

The Uses of Cupric carbonate basic

As seed treatment fungicide; in pyrotechnics; as paint and varnish pigment; in animal and poultry feeds; in sweetening of petrol sour crude stock; in manufacture of other Cu salts.

The Uses of Cupric carbonate basic

Copper(II) carbonate dihydroxide is used as pigments and in treatment for copper deficiency in ruminants. It is also used in pyrotechnics, in sweetening of petrol sour crude stock and animal and poultry feeds. It finds application in some types of make-up such as lipstick. In analytical chemistry, it is used as a reagent for analysis.

Preparation

Basic carbonate is obtained from its naturally occurring minerals. It also may be prepared by mixing a solution of copper sulfate with sodium carbonate. The precipitate is then filtered and dried.

General Description

Copper(II) carbonate basic is naturally found in azurite and malachite. On heating, it undergoes decomposition to form copper(II) oxide, carbon dioxide and water. Due to its high initial discharge capacity, copper(II) carbonate (basic) is being considered as a promising candidate as anode materials for lithium-ion batteries.

Hazard

Toxic by ingestion.

Properties of Cupric carbonate basic

Melting point: 200 °C
Density  4
storage temp.  Sealed in dry,Room Temperature
solubility  Aqueous Acid (Slightly)
form  Solid
Specific Gravity 4.
color  green
Water Solubility  Insoluble
Merck  14,2631
Solubility Product Constant (Ksp) pKsp: 9.86
Exposure limits ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 1 mg/m3
CAS DataBase Reference 12069-69-1(CAS DataBase Reference)
EPA Substance Registry System Copper carbonate, basic (12069-69-1)

Safety information for Cupric carbonate basic

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
ghs
Environment
GHS09
GHS Hazard Statements H319:Serious eye damage/eye irritation
H410:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P273:Avoid release to the environment.
P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for Cupric carbonate basic

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