cis-Dichlorobis(diethylsulfide)platinum(II)
Synonym(s):cis-Bis(diethyl sulfide)platinum(II) chloride;cis-Dichlorobis(1,1′-thiobisethane)platinum
- CAS NO.：15442-57-6
- Empirical Formula: C8H22Cl2PtS2
- Molecular Weight: 448.37
- MDL number: MFCD00050943
- EINECS: 239-454-1
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-02-21 12:36:21
What is cis-Dichlorobis(diethylsulfide)platinum(II)?
Description
Cis-Dichlorobis(diethylsulfide)platinum(II) is a chemical reagent that can prepare other platinum compounds. It is a colorless solid with a melting point of 173°C. cis-Dichlorobis(diethylsulfide)platinum(II) has been used in the synthesis of benzenesulfonyl chloride and benzene, which are essential intermediates for the production of pharmaceuticals such as carbapenems and fluoroquinolones. cis-Dichlorobis(diethylsulfide)platinum(II) also has an isomerization reaction with lithium, ether, or sulfide to yield cis-Dichlorobis(ethylsulfide)platinum (II).
Chemical properties
Yellow-green powder
Properties of cis-Dichlorobis(diethylsulfide)platinum(II)
| Melting point: | 105 °C(lit.) |
| storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
| solubility | Soluble in acetone, alcohol and benzene |
| form | Powder |
| color | yellow |
| Water Solubility | slightly soluble |
| Exposure limits | ACGIH: TWA 0.002 mg/m3 NIOSH: IDLH 4 mg/m3; TWA 0.002 mg/m3 |
| InChI | InChI=1S/2C4H10S.2ClH.Pt/c2*1-3-5-4-2;;;/h2*3-4H2,1-2H3;2*1H; |
| CAS DataBase Reference | 15442-57-6(CAS DataBase Reference) |
Safety information for cis-Dichlorobis(diethylsulfide)platinum(II)
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for cis-Dichlorobis(diethylsulfide)platinum(II)
| InChIKey | UHBPKZLROHZYIJ-UHFFFAOYSA-N |
| SMILES | [Pt+2]([Cl-])([Cl-])(S(CC)CC)S(CC)CC |
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