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HomeProduct name listCIS-4-HEPTENAL

CIS-4-HEPTENAL

  • CAS NO.:6728-31-0
  • Empirical Formula: C7H12O
  • Molecular Weight: 112.17
  • MDL number: MFCD00014682
  • EINECS: 229-779-7
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-07-23 11:40:06
CIS-4-HEPTENAL Structural

What is CIS-4-HEPTENAL?

Description

cis-4-Heptenal has an odor reminiscent of heptaldehyde. It is suggestive of fried fats on dilution. It is used to impart a fried, buttery flavor. It is prepared from Hemiptera insects (trans-form); from pen-ten-l-en-3-ol converted to the corresponding vinyl ether which undergoes a Claisen rearrangement to 4-heptenal (transform).

Chemical properties

clear colorless to light yellow liquid

Chemical properties

(Z)-4-Heptenal is a widespread volatile trace constituent of food flavors. It is a colorless, oily liquidwith a powerful, fatty, somewhat fishy, and, in high dilution, creamy odor. It can be prepared by several ways, for example, by starting from (Z)-3-hexenol.
(Z)-4-Heptenal is used in cream, butter, and fat flavors.

Chemical properties

cis-4-Heptenal has an odor reminiscent of heptaldehyde The odor is suggestive of fried fats on dilution It is used to impart a fried, buttery favor.

Occurrence

Reported found as a constitutent in butterfat, microbial fermented tea and black Hemiptera bugs

The Uses of CIS-4-HEPTENAL

cis-4-Heptenal is an unsaturated aldehyde that possesses a fishy aroma. cis-4-Heptenal is a product of oxidative breakdown of fats in fish, and is naturally found in fish oils.

Preparation

From Hemiptera bugs (trans-form); from penten-1-en-3-ol converted to the corresponding vinyl ether, which undergoes a Claisen rearrangement to 4-heptenal (trans-form).

Aroma threshold values

Detection: 0.4 ppb.

Properties of CIS-4-HEPTENAL

Melting point: -53.35°C (estimate)
Boiling point: 60 °C25 mm Hg(lit.)
Density  0.850 g/mL at 20 °C(lit.)
refractive index  n20/D 1.434
FEMA  3289 | 4-HEPTENAL
Flash point: 105 °F
storage temp.  0-6°C
solubility  Chloroform (Soluble), DMSO (Sparingly), Ethyl Acetate
form  Liquid
color  Clear colorless to light yellow
Odor at 0.10 % in dipropylene glycol. oily fatty green dairy milky creamy
JECFA Number 320
BRN  1902614
Stability: Hygroscopic
CAS DataBase Reference 6728-31-0(CAS DataBase Reference)
EPA Substance Registry System 4-Heptenal, (4Z)- (6728-31-0)

Safety information for CIS-4-HEPTENAL

Signal word Warning
Pictogram(s)
ghs
Flame
Flammables
GHS02
GHS Hazard Statements H226:Flammable liquids
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233:Keep container tightly closed.
P240:Ground/bond container and receiving equipment.
P241:Use explosion-proof electrical/ventilating/lighting/…/equipment.
P242:Use only non-sparking tools.
P243:Take precautionary measures against static discharge.

Computed Descriptors for CIS-4-HEPTENAL

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