CHLOROTITANIUM TRIISOPROPOXIDE

Synonym(s):Chlorotitanium(IV) triisopropoxide;Titanium(IV) chloride triisopropoxide

CAS NO.：20717-86-6
Empirical Formula: C9H21ClO3Ti
Molecular Weight: 260.58
MDL number: MFCD00009861
EINECS: 679-414-4
SAFETY DATA SHEET (SDS)
Update Date: 2023-04-23 13:52:06

CHLOROTITANIUM TRIISOPROPOXIDE Structural

What is CHLOROTITANIUM TRIISOPROPOXIDE?

Chemical properties

Colorless to yellow liquid or low melting solid,

The Uses of CHLOROTITANIUM TRIISOPROPOXIDE

Chlorotriisopropoxytitanium(IV) solution may be used as a precursor for the synthesis of ultralow density ceramic materials. The product may be used to mediate a reductive amination reaction of 5α-cholestane-3,7-dione to yield aryl aminocholestanes.

What are the applications of Application

Chlorotriisopropoxytitanium(IV) is a useful additive for increased regio- and stereocontrol in aldol reactions

Purification Methods

When distilled under vacuum, the distillate sets slowly to a solid on standing. Stock reagents are made by dissolving the warm liquid in pentane, toluene, Et2O, THF, CH2Cl2,, and can be stored in a pure state or in solution under dry N2 for several months. The reagent is hygroscopic and is hydrolysed by H2O. [Reetz et al. Chem Ber 118 1421 1985.]

Properties of CHLOROTITANIUM TRIISOPROPOXIDE

Melting point:	35-40 °C
Boiling point:	63-66°C 0,1mm
Density	1.091 g/mL at 25 °C (lit.)
Flash point:	72 °F
storage temp.	Flammables area
form	liquid
color	fused solid to pale yellow
Specific Gravity	1.091
Hydrolytic Sensitivity	7: reacts slowly with moisture/water
Sensitive	Moisture Sensitive
BRN	4163222
CAS DataBase Reference	20717-86-6(CAS DataBase Reference)
EPA Substance Registry System	Titanium, chlorotris(2-propanolato)-, (T-4)- (20717-86-6)

Safety information for CHLOROTITANIUM TRIISOPROPOXIDE

Signal word	Danger
Pictogram(s)	Flame Flammables GHS02 Corrosion Corrosives GHS05
GHS Hazard Statements	H228:Flammable solids H314:Skin corrosion/irritation
Precautionary Statement Codes	P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P240:Ground/bond container and receiving equipment. P260:Do not breathe dust/fume/gas/mist/vapours/spray. P280:Wear protective gloves/protective clothing/eye protection/face protection. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.