Chlorodimethylphenylsilane
Synonym(s):Dimethylphenylchlorosilane;Dimethylphenylsilylchloride;DMPSCl;Phenyldimethylchlorosilane
- CAS NO.：768-33-2
- Empirical Formula: C8H11ClSi
- Molecular Weight: 170.71
- MDL number: MFCD00000499
- EINECS: 212-193-0
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-06-04 15:29:52
What is Chlorodimethylphenylsilane?
Chemical properties
clear colorless to light yellow liquid
The Uses of Chlorodimethylphenylsilane
Chlorodimethylphenylsilane is used in the synthesis of enantioenriched allenylsilanes through an ortho-ester Claisen rearrangement of chiral and silylpropargylic alcohols.
Purification Methods
Fractionate it through a 1.5 x 18inch column packed with stainless steel helices, or a spinning band column. [Daudt & Hyde J Am Chem Soc 74 386 1952, Lewis et al. J Am Chem Soc 70 1115 1948, Eaborn J Chem Soc 494 1953.] It is used for standardising MeLi or MeMgBr which form Me3PhSi which is estimated by GC. [Maienthal et al. J Am Chem Soc 76 6392 1954, House & Respess J Organomet Chem 4 95 1965, Beilstein 16 IV 1475.] TOXIC and MOISTURE SENSITIVE.
Properties of Chlorodimethylphenylsilane
| Melting point: | <0°C |
| Boiling point: | 194-198 °C |
| Density | 1.017 g/mL at 25 °C(lit.) |
| refractive index | n |
| Flash point: | 143 °F |
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | Miscible with tetrahydrofuran, ether and hexane. |
| form | clear liquid |
| color | Colorless to Light yellow |
| Specific Gravity | 1.017 |
| Water Solubility | MAY DECOMPOSE |
| Sensitive | Moisture Sensitive |
| Hydrolytic Sensitivity | 8: reacts rapidly with moisture, water, protic solvents |
| BRN | 606292 |
| CAS DataBase Reference | 768-33-2(CAS DataBase Reference) |
| NIST Chemistry Reference | Silane, chlorodimethylphenyl-(768-33-2) |
| EPA Substance Registry System | Silane, chlorodimethylphenyl- (768-33-2) |
Safety information for Chlorodimethylphenylsilane
| Signal word | Danger |
| Pictogram(s) |
 Corrosion Corrosives GHS05 |
| GHS Hazard Statements |
H314:Skin corrosion/irritation |
| Precautionary Statement Codes |
P280:Wear protective gloves/protective clothing/eye protection/face protection. P363:Wash contaminated clothing before reuse. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P405:Store locked up. |
Computed Descriptors for Chlorodimethylphenylsilane
| InChIKey | KWYZNESIGBQHJK-UHFFFAOYSA-N |
New Products
4-Aminotetrahydropyran-4-carbonitrile Hydrochloride (R)-3-Aminobutanenitrile Hydrochloride 4-AMINO-TETRAHYDRO-PYRAN-4-CARBOXYLIC ACID HCL 4-(Dimethylamino)tetrahydro-2H-pyran-4-carbonitrile 3-((Dimethylamino)methyl)-5-methylhexan-2-one oxalate 1,4-Dioxa-8-azaspiro[4.5]decane 5-Bromo-2-nitropyridine Nimesulide BP Aceclofenac IP/BP/EP Diclofenac Sodium IP/BP/EP/USP Mefenamic Acid IP/BP/EP/USP Ornidazole IP Diclofenac Potassium SODIUM AAS SOLUTION ZINC AAS SOLUTION BUFFER SOLUTION PH 10.0(BORATE) GOOCH CRUCIBLE SINTERED AQUANIL 5 BERYLLIUM AAS SOLUTION 2-Bromo-1-(bromomethyl)-3-chloro-5-nitrobenzene 2-Bromo-3-nitroaniline N-(3-Hydroxypropyl)-N-methylacetamide 3-Bromo-6-chloropyridazine 4-ethyl-3-nitrobenzoic acidRelated products of tetrahydrofuran
You may like
-
Chlorodimethylphenylsilane CAS 768-33-2View Details
768-33-2 -
Chloro(dimethyl)phenylsilane CAS 768-33-2View Details
768-33-2 -
Chloro(dimethyl)phenylsilane 97.00% CAS 768-33-2View Details
768-33-2 -
1823368-42-8 98%View Details
1823368-42-8 -
2-(3-(tert-butyl)phenoxy)-2-methylpropanoic acid 1307449-08-6 98%View Details
1307449-08-6 -
Ethyl 3-(furan-2-yl)-3-hydroxypropanoate 25408-95-1 98%View Details
25408-95-1 -
2-Chloro-5-fluoro-1-methoxy-3-methylbenzene 98%View Details
1805639-70-6 -
Lithium ClavulanateView Details
61177-44-4
Statement: All products displayed on this website are only used for non medical purposes such as industrial applications or scientific research, and cannot be used for clinical diagnosis or treatment of humans or animals. They are not medicinal or edible.