CERIUM(III) CHLORIDE HEPTAHYDRATE
Synonym(s):Cerium trichloride heptahydrate;Cerous chloride heptahydrate
- CAS NO.:18618-55-8
- Empirical Formula: CeCl3H14O7
- Molecular Weight: 372.58
- MDL number: MFCD00149634
- EINECS: 606-073-0
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-11-14 14:09:35
What is CERIUM(III) CHLORIDE HEPTAHYDRATE?
Chemical properties
colourless crystalline solid
The Uses of CERIUM(III) CHLORIDE HEPTAHYDRATE
Cerium(III) chloride heptahydrate can be used in the conversion of esters to allylsilanes.
The Uses of CERIUM(III) CHLORIDE HEPTAHYDRATE
Cerium(III) chloride heptahydrate is used in the preparation of allylsilanes from esters. It is used as a reducing agent in organic synthesis in place of sodium borohydride. In Luche reaction, carvone gives selectively allylic alcohol.
The Uses of CERIUM(III) CHLORIDE HEPTAHYDRATE
Catalyst employed in a solvent-free microwave-assisted synthesis of 2-quinolones via condensation of ?-ketoesters with o-anilinoketones. Coupled with NaI promotes the Beckmann rearrangement of oximes.
What are the applications of Application
Cerium(III) chloride heptahydrate is used in the conversion of esters to allylsilanes
General Description
Cerium(III) chloride heptahydrate is a mild Lewis acid. It participates in the allylation of aldehydes. Cerium(III) chloride heptahydrate in combination with sodium iodide supported on silica gel efficiently promotes Michael-type addition. Cerium(III) chloride heptahydrate in the presence of sodium iodide acts as an efficient catalyst for the Michael addition of 1,3-dicarbonyl compounds to α,β-unsaturated ketones and α,β-unsaturated aldehydes.
Properties of CERIUM(III) CHLORIDE HEPTAHYDRATE
Melting point: | 848 °C |
Density | ~3.94 g/mL at 25 °C(lit.) |
storage temp. | Inert atmosphere,Room Temperature |
solubility | very soluble in H2O, ethanol |
form | Crystals or Crystalline Powder |
color | Light yellow |
Odor Threshold | Stinging odor |
Water Solubility | Soluble in alcohol, water, and acetone. Slightly soluble in tetrahydrofuran. |
Sensitive | Hygroscopic |
Merck | 14,1997 |
Stability: | Stable, but may be moisture sensitive. Incompatible with strong acids, strong oxidizing agents. |
CAS DataBase Reference | 18618-55-8(CAS DataBase Reference) |
Safety information for CERIUM(III) CHLORIDE HEPTAHYDRATE
Signal word | Danger |
Pictogram(s) |
Corrosion Corrosives GHS05 Environment GHS09 |
GHS Hazard Statements |
H314:Skin corrosion/irritation H410:Hazardous to the aquatic environment, long-term hazard |
Precautionary Statement Codes |
P260:Do not breathe dust/fume/gas/mist/vapours/spray. P273:Avoid release to the environment. P280:Wear protective gloves/protective clothing/eye protection/face protection. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. |
Computed Descriptors for CERIUM(III) CHLORIDE HEPTAHYDRATE
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