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HomeProduct name listBis(tetrabutylammonium) dichromate

Bis(tetrabutylammonium) dichromate

Synonym(s):TBADC;Tetrabutylammonium dichromate

  • CAS NO.:56660-19-6
  • Empirical Formula: C32H72Cr2N2O7
  • Molecular Weight: 700.92
  • MDL number: MFCD00013104
  • EINECS: 260-315-6
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-04-23 13:52:06
Bis(tetrabutylammonium) dichromate Structural

What is Bis(tetrabutylammonium) dichromate?

The Uses of Bis(tetrabutylammonium) dichromate

Reagent for:

  • Preparation of nitrophenol derivatives and quinones under aprotic reaction conditions
  • Conversion of oximes to carbonyl compounds under microwave irradiation

  • Catalyst precursor for catalytic gas phase dehydration of acetic acid to ketene
  • Crosslinking agent

Purification Methods

Wash it with water and dry it in a vacuum. Recrystallise it from hexane (m 79-80o). [Santaniello & Ferraboschi Synth Commun 10 75 1980, Beilstein 4 IV 556.] (Possible CARCINOGEN.)

Properties of Bis(tetrabutylammonium) dichromate

Melting point: 139-143 °C (lit.)
form  powder to crystaline
color  Light yellow to Brown
Water Solubility  Soluble in water.
Exposure limits OSHA: Ceiling 0.1 mg/m3
NIOSH: IDLH 15 mg/m3; TWA 0.0002 mg/m3

Safety information for Bis(tetrabutylammonium) dichromate

Signal word Danger
Pictogram(s)
ghs
Flame Over Circle
Oxidizers
GHS03
ghs
Exclamation Mark
Irritant
GHS07
ghs
Health Hazard
GHS08
ghs
Environment
GHS09
GHS Hazard Statements H272:Oxidising liquids;Oxidising solids
H317:Sensitisation, Skin
H350:Carcinogenicity
H410:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P202:Do not handle until all safety precautions have been read and understood.
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P273:Avoid release to the environment.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P308+P313:IF exposed or concerned: Get medical advice/attention.

Computed Descriptors for Bis(tetrabutylammonium) dichromate

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