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HomeProduct name listBIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER

BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER

Synonym(s):[Ir(coe)2Cl]2;Di-μ-chlorotetrakis(cyclooctene)diiridium

BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER Structural

What is BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER?

Chemical properties

Yellow solid

The Uses of BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER

Chlorobis(cyclooctene)iridium(I) dime is used as catalyst for Isomerization-hydroboration reactions with nido-carboranyldiphosphine as stabilizing ligand, Hydrogen peroxide oxidation of hydroxamic acids and their subsequent hetero Diels-Alder cycloaddition reactions, Immobilization of organic functional groups onto solid supports through vinylsilane coupling reactions, Alkylation reactions, Guerbet reaction, Allylic amination reactions in a DNA-diene-iridium(I) hybrid system, Asymmetric hydroamination reactions.

What are the applications of Application

Chlorobis(cyclooctene)iridium(I)dimer is a catalyst for many reactions, including alkylation reactions and Guerbet reactions

Properties of BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER

Melting point: 160-165 °C (dec.) (lit.)
storage temp.  under inert gas (nitrogen or Argon) at 2-8°C
solubility  Soluble in organic solvents.
form  crystal
color  yellow
Sensitive  moisture sensitive, store cold

Safety information for BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P271:Use only outdoors or in a well-ventilated area.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER

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