BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER

Synonym(s):[Ir(coe)₂Cl]₂;Di-μ-chlorotetrakis(cyclooctene)diiridium

CAS NO.：12246-51-4
Empirical Formula: C32H56Cl2Ir28*
Molecular Weight: 896.13
MDL number: MFCD00213465
SAFETY DATA SHEET (SDS)
Update Date: 2024-04-28 19:50:54

BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER Structural

What is BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER?

Chemical properties

Yellow solid

The Uses of BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER

Chlorobis(cyclooctene)iridium(I) dime is used as catalyst for Isomerization-hydroboration reactions with nido-carboranyldiphosphine as stabilizing ligand, Hydrogen peroxide oxidation of hydroxamic acids and their subsequent hetero Diels-Alder cycloaddition reactions, Immobilization of organic functional groups onto solid supports through vinylsilane coupling reactions, Alkylation reactions, Guerbet reaction, Allylic amination reactions in a DNA-diene-iridium(I) hybrid system, Asymmetric hydroamination reactions.

What are the applications of Application

Chlorobis(cyclooctene)iridium(I)dimer is a catalyst for many reactions, including alkylation reactions and Guerbet reactions

Properties of BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER

Melting point:	160-165 °C (dec.) (lit.)
storage temp.	under inert gas (nitrogen or Argon) at 2-8°C
solubility	Soluble in organic solvents.
form	crystal
color	yellow
Sensitive	moisture sensitive, store cold

Safety information for BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER

Signal word	Warning
Pictogram(s)	Exclamation Mark Irritant GHS07
GHS Hazard Statements	H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes	P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.