Bis(2,4-pentanedionato-O,O')palladium(II)

Synonym(s):Bis(acetylacetonato)palladium(II), Bis(2,4-pentanedionato) palladium(II);Diacetylacetonatopalladium(II);Palladium(II) 2,4-pentanedionate;Palladium(II) acetylacetonate;Pd(acac)₂

CAS NO.：14024-61-4
Empirical Formula: C10H14O4Pd
Molecular Weight: 304.64
MDL number: MFCD00000025
EINECS: 237-859-8
SAFETY DATA SHEET (SDS)
Update Date: 2024-09-12 12:58:43

Bis(2,4-pentanedionato-O,O')palladium(II) Structural

What is Bis(2,4-pentanedionato-O,O')palladium(II)?

Chemical properties

yellow orange needles

The Uses of Bis(2,4-pentanedionato-O,O')palladium(II)

Palladium(II) Acetylacetonate is an active anticancer agent. Exhibits growth inhibitory effect more than cisplatin in several cancer cells and treatment with Palladium(II) Acetylacetonate inhibits H460 cells. Palladium(II) Acetylacetonate is a catalyst for various organic transformations.

The Uses of Bis(2,4-pentanedionato-O,O')palladium(II)

Palladium(II) acetylacetonate (Pd(acac)₂) was used in the following studies:

Typical high-temperature organic solution phase protocol for the preparation of monodisperse CuPd alloy nanoparticles (NPs).
Preparation of [(NHC)Pd(acac)L] (where L=Me, NHC = N-heterocyclic carbene) complexes. These complexes efficiently catalyze the Heck reaction of activated aryl bromides.
As catalyst in the decarboxylative cross-coupling of arylcarboxylic acids with aryl halides.

What are the applications of Application

Palladium(II) acetylacetonate is a catalyst for decarboxylative cross-coupling reactions

General Description

Palladium(II) acetylacetonate (Pd(acac)₂) is a metal-organic complex. Sublimation of Pd(acac)₂ has been investigated by thermogravimetry and XRD. The temperature range for the sublimation of Pd(acac)₂, without undergoing thermal decomposition, was determined to be 100-160°C in the presence of inert gas helium.

Flammability and Explosibility

Highly flammable

Purification Methods

It can be recrystallised from *C6H6/pet ether and sublimes in vacuo. It is soluble in heptane, *C6H6 (1.2% at 20o, 2.2 at 40o), toluene (0.56% at 20o, 1.4% at 40o) and acetylacetone (1.2% at 20o, 0.05% at 40o). [West & Riley J Inorg Nucl Chem 5 295 1957/8, Fernelius & Bryant Inorg Synth V 105 1957, Beilstein 1 IV 3676.]

Properties of Bis(2,4-pentanedionato-O,O')palladium(II)

Melting point:	190 °C
vapor pressure	0Pa at 25℃
storage temp.	Store below +30°C.
solubility	Soluble in benzene and chloroform.
form	Solution
color	Yellow to orange
Specific Gravity	1.862
Water Solubility	INSOLUBLE
Hydrolytic Sensitivity	4: no reaction with water under neutral conditions
BRN	4136188
NIST Chemistry Reference	Bis(acetylacetonato)palladium(14024-61-4)
EPA Substance Registry System	Palladium, bis(2,4-pentanedionato-.kappa.O,.kappa.O')-, (SP-4-1)- (14024-61-4)

Safety information for Bis(2,4-pentanedionato-O,O')palladium(II)

Signal word	Warning
Pictogram(s)	Exclamation Mark Irritant GHS07
GHS Hazard Statements	H319:Serious eye damage/eye irritation
Precautionary Statement Codes	P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.