Bis(2,4-pentanedionato-O,O')palladium(II)
Synonym(s):Bis(acetylacetonato)palladium(II), Bis(2,4-pentanedionato) palladium(II);Diacetylacetonatopalladium(II);Palladium(II) 2,4-pentanedionate;Palladium(II) acetylacetonate;Pd(acac)2
- CAS NO.：14024-61-4
- Empirical Formula: C10H14O4Pd
- Molecular Weight: 304.64
- MDL number: MFCD00000025
- EINECS: 237-859-8
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-12-18 14:08:52
What is Bis(2,4-pentanedionato-O,O')palladium(II)?
Chemical properties
yellow orange needles
The Uses of Bis(2,4-pentanedionato-O,O')palladium(II)
Palladium(II) Acetylacetonate is an active anticancer agent. Exhibits growth inhibitory effect more than cisplatin in several cancer cells and treatment with Palladium(II) Acetylacetonate inhibits H460 cells. Palladium(II) Acetylacetonate is a catalyst for various organic transformations.
The Uses of Bis(2,4-pentanedionato-O,O')palladium(II)
Palladium(II) acetylacetonate (Pd(acac)2) was used in the following studies:
- Typical high-temperature organic solution phase protocol for the preparation of monodisperse CuPd alloy nanoparticles (NPs).
- Preparation of [(NHC)Pd(acac)L] (where L=Me, NHC = N-heterocyclic carbene) complexes. These complexes efficiently catalyze the Heck reaction of activated aryl bromides.
- As catalyst in the decarboxylative cross-coupling of arylcarboxylic acids with aryl halides.
What are the applications of Application
Palladium(II) acetylacetonate is a catalyst for decarboxylative cross-coupling reactions
General Description
Palladium(II) acetylacetonate (Pd(acac)2) is a metal-organic complex. Sublimation of Pd(acac)2 has been investigated by thermogravimetry and XRD. The temperature range for the sublimation of Pd(acac)2, without undergoing thermal decomposition, was determined to be 100-160°C in the presence of inert gas helium.
Flammability and Explosibility
Highly flammable
Purification Methods
It can be recrystallised from *C6H6/pet ether and sublimes in vacuo. It is soluble in heptane, *C6H6 (1.2% at 20o, 2.2 at 40o), toluene (0.56% at 20o, 1.4% at 40o) and acetylacetone (1.2% at 20o, 0.05% at 40o). [West & Riley J Inorg Nucl Chem 5 295 1957/8, Fernelius & Bryant Inorg Synth V 105 1957, Beilstein 1 IV 3676.]
Properties of Bis(2,4-pentanedionato-O,O')palladium(II)
| Melting point: | 190 °C |
| vapor pressure | 0Pa at 25℃ |
| storage temp. | Store below +30°C. |
| solubility | Soluble in benzene and chloroform. |
| form | Solution |
| color | Yellow to orange |
| Specific Gravity | 1.862 |
| Water Solubility | INSOLUBLE |
| Hydrolytic Sensitivity | 4: no reaction with water under neutral conditions |
| BRN | 4136188 |
| NIST Chemistry Reference | Bis(acetylacetonato)palladium(14024-61-4) |
| EPA Substance Registry System | Palladium, bis(2,4-pentanedionato-.kappa.O,.kappa.O')-, (SP-4-1)- (14024-61-4) |
Safety information for Bis(2,4-pentanedionato-O,O')palladium(II)
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H319:Serious eye damage/eye irritation |
| Precautionary Statement Codes |
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for Bis(2,4-pentanedionato-O,O')palladium(II)
| InChIKey | RJJXYEQOOACRKP-LNKPDPKZSA-M |
Bis(2,4-pentanedionato-O,O')palladium(II) manufacturer
Vineeth Precious Catalysts Pvt Ltd
1Y
Phone:+91-9049600004
Whatsapp: +91 9049600004
product: 14024-61-4 / 38420-73-4 Palladium(II) acetylacetonate 99%
Metal Chem India
1Y
Phone:+91-9011882000
Whatsapp: +91-9011882000
product: Palladium(II) acetylacetonate 98%
Johnson Matthey Chemicals India Pvt Ltd
1Y
Phone:+91-9711869003
Whatsapp: +91-9711869003
product: Palladium(II) acetylacetonate 14024-61-4 / 38420-73-4 98%
Vineeth Precious Catalysts Pvt. Ltd.
Maharashtra
Phone:91-8149095778
Whatsapp: 91-8149095778
product: Palladium(II) acetylacetonate
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