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HomeProduct name listVanadyl acetylacetonate

Vanadyl acetylacetonate

Synonym(s):Bis(acetylacetonato)vanadium(IV) oxide, Bis(2,4-pentanedionato)vanadium(IV) oxide;Vanadium(IV) oxide acetylacetonate;Vanadium(IV)-oxy acetylacetonate;VO(acac)2

  • CAS NO.:3153-26-2
  • Empirical Formula: C10H14O5V
  • Molecular Weight: 265.16
  • MDL number: MFCD00000032
  • EINECS: 221-590-8
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-10-30 18:52:02
Vanadyl acetylacetonate Structural

What is Vanadyl acetylacetonate?

Chemical properties

powder

The Uses of Vanadyl acetylacetonate

Vanadyl acetylacetonate may be used as a precursor for the preparation of vanadium dioxide thin films for applications in “intelligent” window coating and data storage.

The Uses of Vanadyl acetylacetonate

Vanadium(IV) Oxide Acetylacetonate is used as a catalyst in organic chemistry and is also an intermediate in synthetic reactions, such as the synthesis of novel oxovanadium complexes that display antitumor activity.

Flammability and Explosibility

Not classified

Purification Methods

It crystallises from acetone. [cf Fernelius & Bryant Inorg Synth V 105 1957, Beilstein 1 IV 3672.]

Properties of Vanadyl acetylacetonate

Melting point: 235 °C (dec.)(lit.)
Boiling point: 140°C 13mm
Density  1,4 g/cm3
vapor pressure  0Pa at 20℃
Flash point: 79 °C
storage temp.  Store below +30°C.
solubility  Moderately soluble in acetone, ether and chloroform. Soluble in ethanol and benzene
form  Crystalline Powder
color  Green to blue-green
Specific Gravity 1.4
Water Solubility  practically insoluble
Hydrolytic Sensitivity 4: no reaction with water under neutral conditions
BRN  4138236
Exposure limits NIOSH: Ceiling 0.05 mg/m3
Stability: Stable, but air sensitive. May discolour upon exposure to air. Incompatible with strong oxidizing agents.
CAS DataBase Reference 3153-26-2(CAS DataBase Reference)
NIST Chemistry Reference Bis(2,4-pentanedionato)oxovanadium(iv)(3153-26-2)
EPA Substance Registry System Vanadium, oxobis(2,4-pentanedionato-.kappa.O,.kappa.O')-, (SP-5-21)- (3153-26-2)

Safety information for Vanadyl acetylacetonate

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H302:Acute toxicity,oral
H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P270:Do not eat, drink or smoke when using this product.
P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for Vanadyl acetylacetonate

InChIKey JFHJZWAQYMGNBE-SUKNRPLKSA-L

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