Vanadyl acetylacetonate
Synonym(s):Bis(acetylacetonato)vanadium(IV) oxide, Bis(2,4-pentanedionato)vanadium(IV) oxide;Vanadium(IV) oxide acetylacetonate;Vanadium(IV)-oxy acetylacetonate;VO(acac)2
- CAS NO.：3153-26-2
- Empirical Formula: C10H14O5V
- Molecular Weight: 265.16
- MDL number: MFCD00000032
- EINECS: 221-590-8
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-08-22 14:21:17
What is Vanadyl acetylacetonate?
Chemical properties
powder
The Uses of Vanadyl acetylacetonate
Vanadyl acetylacetonate may be used as a precursor for the preparation of vanadium dioxide thin films for applications in “intelligent” window coating and data storage.
The Uses of Vanadyl acetylacetonate
Vanadium(IV) Oxide Acetylacetonate is used as a catalyst in organic chemistry and is also an intermediate in synthetic reactions, such as the synthesis of novel oxovanadium complexes that display antitumor activity.
Flammability and Explosibility
Not classified
Purification Methods
It crystallises from acetone. [cf Fernelius & Bryant Inorg Synth V 105 1957, Beilstein 1 IV 3672.]
Properties of Vanadyl acetylacetonate
| Melting point: | 235 °C (dec.)(lit.) |
| Boiling point: | 140°C 13mm |
| Density | 1,4 g/cm3 |
| vapor pressure | 0Pa at 20℃ |
| Flash point: | 79 °C |
| storage temp. | Store below +30°C. |
| solubility | Moderately soluble in acetone, ether and chloroform. Soluble in ethanol and benzene |
| form | Crystalline Powder |
| color | Green to blue-green |
| Specific Gravity | 1.4 |
| Water Solubility | practically insoluble |
| Hydrolytic Sensitivity | 4: no reaction with water under neutral conditions |
| BRN | 4138236 |
| Exposure limits | NIOSH: Ceiling 0.05 mg/m3 |
| Stability: | Stable, but air sensitive. May discolour upon exposure to air. Incompatible with strong oxidizing agents. |
| CAS DataBase Reference | 3153-26-2(CAS DataBase Reference) |
| NIST Chemistry Reference | Bis(2,4-pentanedionato)oxovanadium(iv)(3153-26-2) |
| EPA Substance Registry System | Vanadium, oxobis(2,4-pentanedionato-.kappa.O,.kappa.O')-, (SP-5-21)- (3153-26-2) |
Safety information for Vanadyl acetylacetonate
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H302:Acute toxicity,oral H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P270:Do not eat, drink or smoke when using this product. P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for Vanadyl acetylacetonate
| InChIKey | JFHJZWAQYMGNBE-SUKNRPLKSA-L |
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