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HomeProduct name listBIPHENYLENE

BIPHENYLENE

Synonym(s):Diphenylene

BIPHENYLENE Structural

What is BIPHENYLENE?

Chemical properties

YELLOW NEEDLES

Definition

ChEBI: Biphenylene is an ortho-fused polycyclic arene and an ortho-fused tricyclic hydrocarbon.

Purification Methods

Biphenylene from yellow crystals from cyclohexane, MeOH (m 110-111o) or EtOH (m 111-112o). It sublimes in vacuo. The 2,4,7-trinitrofluorenone complex has m 154o and the picrate gives red needles m 122o from EtOH. [Beilstein 5 I 298, 5 II 530, 5 III 1935, 5 IV 2137.]

Properties of BIPHENYLENE

Melting point: 113-114 °C (lit.)
Boiling point: 262℃
Density  1.190
refractive index  1.4840 (estimate)
Flash point: 100℃
storage temp.  Sealed in dry,Room Temperature
form  Needles
color  Yellow
EPA Substance Registry System Biphenylene (259-79-0)

Safety information for BIPHENYLENE

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H302:Acute toxicity,oral
H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for BIPHENYLENE

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