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HomeProduct name listBenzyltriphenylphosphonium bromide

Benzyltriphenylphosphonium bromide

Synonym(s):(Phenylmethyl)triphenylphosphonium bromide;Bromo(benzyl)triphenylphosphorane;NSC 54813

  • CAS NO.:1449-46-3
  • Empirical Formula: C25H22BrP
  • Molecular Weight: 433.32
  • MDL number: MFCD00031707
  • EINECS: 215-908-4
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-09-04 11:52:49
Benzyltriphenylphosphonium bromide Structural

What is Benzyltriphenylphosphonium bromide?

Chemical properties

WHITE CRYSTALLINE POWDER

The Uses of Benzyltriphenylphosphonium bromide

Benzyltriphenylphosphonium bromide is used as a reactant for stereoselective azidolysis of vinyl epoxides, enantioselective aziridination and Friedel-Crafts cyclization for asymmetric synthesis of dihydrexidine, biomimetic iron(III) mediated oxidative dimerization for synthesis of benzoquinone parvistemin A, enantioselective synthesis of syn-diarylheptanoids from D-glucose, preparation of β-amyloid plaque ligands and decarboxylative cyclopropanation. It react with 4-methyl-oxetan-2-one to produce 4-hydroxy-1-phenyl-1-(triphenyl-l5-phosphanylidene)-pentan-2-one.

Properties of Benzyltriphenylphosphonium bromide

Melting point: 295-298 °C(lit.)
storage temp.  Inert atmosphere,Room Temperature
form  solid
color  White to Almost white
Water Solubility  Soluble in water.
Sensitive  Hygroscopic
BRN  3599867
CAS DataBase Reference 1449-46-3(CAS DataBase Reference)

Safety information for Benzyltriphenylphosphonium bromide

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P271:Use only outdoors or in a well-ventilated area.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for Benzyltriphenylphosphonium bromide

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