Benzophenone imine

CAS NO.：1013-88-3
Empirical Formula: C13H11N
Molecular Weight: 181.23
MDL number: MFCD00001760
EINECS: 440-870-2
SAFETY DATA SHEET (SDS)
Update Date: 2024-11-01 18:09:03

What is Benzophenone imine?

Description

Benzophenone imine is commonly used as an ammonia surrogate.

Chemical properties

clear colorless to light yellow-brownish liquid

The Uses of Benzophenone imine

Benzophenone imine is useful in the preparation of nitrile ylide dimers.

The Uses of Benzophenone imine

Useful in the preparation of nitrile ylide dimers.Benzophenone imine as ammonia surrogate. As intermediate material for synthesis of organic chemicals. Catalytic enantioselective alkylation of the benzophenone imine of glycine t-butyl ester using phosphazene (Schwesinger) bases and chiral quaternary ammonium salts yields either enantiomer of amino acid derivatives in excellent yield.

What are the applications of Application

Benzophenone imine is a starting material for nitrile ylide dimers

Synthesis Reference(s)

Synthetic Communications, 18, p. 1501, 1988 DOI: 10.1080/00397918808081307

Flammability and Explosibility

Not classified

Properties of Benzophenone imine

Melting point:	-30 °C
Boiling point:	151-153 °C10 mm Hg(lit.)
Density	1.08 g/mL at 25 °C(lit.)
vapor pressure	0.082Pa at 20℃
refractive index	n20/D 1.618(lit.)
Flash point:	145 °C
storage temp.	Inert atmosphere,Room Temperature
solubility	DMSO (Slightly), Ethyl Acetate (Slightly)
appearance	Colorless to light-yellow liquid
form	Liquid
pka	pK1:6.82 (25°C)
color	Clear colorless to light yellow-brownish
Water Solubility	0.3 g/L (25 ºC)
BRN	1100371
CAS DataBase Reference	1013-88-3(CAS DataBase Reference)
NIST Chemistry Reference	Benzenemethanimine, «alpha»-phenyl-(1013-88-3)

Safety information for Benzophenone imine

Signal word	Warning
Pictogram(s)	Exclamation Mark Irritant GHS07
GHS Hazard Statements	H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes	P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.