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HomeProduct name listBENZENE CHROMIUM TRICARBONYL

BENZENE CHROMIUM TRICARBONYL

Synonym(s):Benchrotrene;Benzene-tricarbonylchromium(0)

  • CAS NO.:12082-08-5
  • Empirical Formula: C9H6CrO36*
  • Molecular Weight: 214.14
  • MDL number: MFCD00009955
  • EINECS: 235-146-6
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-04-23 13:52:06
BENZENE CHROMIUM TRICARBONYL Structural

What is BENZENE CHROMIUM TRICARBONYL?

Chemical properties

yellow crystalline powder

The Uses of BENZENE CHROMIUM TRICARBONYL

Catalyst for:

  • Oxidation of alkenes
  • Hydrogenation of alkynes

Purification Methods

Purify the complex by sublimation in vacuo. A possible impurity is 2-picoline which can be removed by washing with pentane and drying. It is then purified further by sublimation at 80-85o/10-3mm, or by recrystallisation from Et2O to give yellow crystals. 1H NMR in CDCl3 should give a single peak at 4.68. [Rausch J Org Chem 39 1787 1974, Pauson in Houben-Weyl Meth Org Chem V, E 18 Pt I p226 Theme Verlag, Stuttgart 1986, Beilstein 5 IV 625.]

Properties of BENZENE CHROMIUM TRICARBONYL

Melting point: 163-166 °C (lit.)
form  crystal
color  yellow
BRN  3571699

Safety information for BENZENE CHROMIUM TRICARBONYL

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

Computed Descriptors for BENZENE CHROMIUM TRICARBONYL

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