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HomeProduct name listALLYLDIPHENYLPHOSPHINE OXIDE

ALLYLDIPHENYLPHOSPHINE OXIDE

Synonym(s):Diphenyl-2-propenylphosphine oxide;NSC 616249;NSC 98715

ALLYLDIPHENYLPHOSPHINE OXIDE Structural

What is ALLYLDIPHENYLPHOSPHINE OXIDE?

The Uses of ALLYLDIPHENYLPHOSPHINE OXIDE

Reactant for:

  • Preparaton of a-substituted alkylsilanes via regio- and chemoselective copper-catalyzed silylzincation and electrophilic substitution from terminal alkenes, and prepn. of α-substituted alcohols via Fleming-Tamao oxidation of alkylsilanes
  • Olefin isomerization with Grubbs′ catalysts occluded in a hydrophobic matrix of polydimethylsiloxane (PDMS)
  • C9-substituted trans-hydrindene via diastereotopic group-selective intramolecular Diels-Alder reaction
  • Isomerization of allyl group-containing compounds to propenyl group-containing compounds in the presence of a Grubbs second-generation Ru catalyst
  • Ruthenium-catalyzed olefin cross-metathesis of vinyl and allyl phosphine oxides to give alkenyl phosphine oxides and bis-phosphine oxides

What are the applications of Application

Allyldiphenylphosphine oxide is a synthesis reagent

Properties of ALLYLDIPHENYLPHOSPHINE OXIDE

Melting point: 110-114 °C(lit.)
Boiling point: 200-202 °C(Press: 2 Torr)
Density  1.0769 g/cm3
storage temp.  under inert gas (nitrogen or Argon) at 2-8°C
form  solid

Safety information for ALLYLDIPHENYLPHOSPHINE OXIDE

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
Precautionary Statement Codes P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P280:Wear protective gloves/protective clothing/eye protection/face protection.

Computed Descriptors for ALLYLDIPHENYLPHOSPHINE OXIDE

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