Allyl methacrylate

CAS NO.：96-05-9
Empirical Formula: C7H10O2
Molecular Weight: 126.15
MDL number: MFCD00008592
EINECS: 202-473-0
SAFETY DATA SHEET (SDS)
Update Date: 2024-08-26 21:18:56

What is Allyl methacrylate?

Chemical properties

Allyl Methacrylate is water-insoluble, with low volatility clear liquid.

The Uses of Allyl methacrylate

Allyl methacrylate is an important cross-linking agent that provides effective bifunctional cross-linking in the second stage, with good chemical resistance, impact strength, adhesion, hardness and low shrinkage. Used in dental materials, industrial paints, silicone intermediates, light stabilizers, optical polymers, elastomers and some vinyl and acrylate polymer systems. It is also used in oil additives as flow improver, in-floor waxes, textile and metal coatings, paint, varnishes, pressure-sensitive adhesives, low temperature caulks, and sealants.

Preparation

Allyl methacrylate can be synthesized by the reaction of acrylamide and allyl alcohol under the action of concentrated acid and H2O2. It can also be obtained by transesterification of allyl acetate and methyl methacrylate.

What are the applications of Application

Allyl Methacrylate (AMA) is a very useful starting material for chemical synthesis since it easily undergoes addition reactions with a wide spectrum of organic and inorganic compounds. It is used mainly in closed system processing as a co-monomer (rigid plastics) and cross linker (silanes).

General Description

Allyl methacrylate (AMA) is an acrylic monomer with two types of vinyl groups which include methacrylic and allylic based double bonds. It is mainly utilized as a cross-linking agent to increase the hardness of the base material. It also facilitates an improvement in the heat resistant property of the resin.

Properties of Allyl methacrylate

Melting point:	-65 °C
Boiling point:	59-61 °C/43 mmHg (lit.)
Density	0.938 g/mL at 25 °C (lit.)
vapor pressure	4.6 mm Hg ( 20 °C)
refractive index	n20/D 1.436(lit.)
Flash point:	93 °F
storage temp.	2-8°C
form	Liquid
color	Clear
Specific Gravity	0.938
Water Solubility	4 g/L (20 ºC)
BRN	1747406
CAS DataBase Reference	96-05-9(CAS DataBase Reference)
NIST Chemistry Reference	2-Propenoic acid, 2-methyl-, 2-propenyl ester(96-05-9)
EPA Substance Registry System	Allyl methacrylate (96-05-9)

Safety information for Allyl methacrylate

Signal word	Danger
Pictogram(s)	Flame Flammables GHS02 Skull and Crossbones Acute Toxicity GHS06 Health Hazard GHS08 Environment GHS09
GHS Hazard Statements	H226:Flammable liquids H302:Acute toxicity,oral H311:Acute toxicity,dermal H330:Acute toxicity,inhalation H373:Specific target organ toxicity, repeated exposure H410:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes	P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P273:Avoid release to the environment. P280:Wear protective gloves/protective clothing/eye protection/face protection. P314:Get medical advice/attention if you feel unwell. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.