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HomeProduct name listAcetophenone oxime

Acetophenone oxime

  • CAS NO.:613-91-2
  • Empirical Formula: C8H9NO
  • Molecular Weight: 135.16
  • MDL number: MFCD00013931
  • EINECS: 210-360-2
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-05-09 09:30:21
Acetophenone oxime Structural

What is Acetophenone oxime?

Description

Acetophenone oxime is a solid but slightly soluble substance. Acetophenone oxime is incompatible with strong oxidising agents, moisture, acids, and metal and alkali compounds. Acetophenone oxime on decomposition releases irritating and toxic fumes and gases. There is no published data about the hazardous polymerisation of acetophenone oxime.

Chemical properties

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Chemical properties

Acetophenone oxime is a solid but slightly soluble substance. It is incompatible with strong oxidizing agents, moisture, acids, metal, and alkali compounds. On decomposition, acetophenone oxime releases irritating and toxic fumes and gases. There are no published data about the hazardous polymerization of acetophenone oxime.

The Uses of Acetophenone oxime

1-Phenylethanone Oxime is a useful reagent for organic synthesis

Synthesis Reference(s)

The Journal of Organic Chemistry, 52, p. 5089, 1987 DOI: 10.1021/jo00232a005
Tetrahedron Letters, 30, p. 5763, 1989 DOI: 10.1016/S0040-4039(00)76191-0

Health Hazard

Exposures to acetophenone oxime cause irritation to the eyes, skin, and the respiratory and digestive tracts. The toxicological properties of acetophenone oxime are not been fully investigated.

Safety Profile

Poison by an unspecified route.Slightly toxic by ingestion. When heated to decomposition itemits toxic vapors of NOx.

storage

Acetophenone oxime should be kept stored in a cool, dry place and in a closed container when not in use.

Precautions

On exposures to acetophenone oxime, occupational workers should immediately fl ush the eyes with plenty of water. Workers should use proper personal protective equipment, wear appropriate gloves to prevent skin exposure, and wear appropriate protective eyeglasses or chemical safety goggles as described.

Properties of Acetophenone oxime

Melting point: 55-60 °C (lit.)
Boiling point: 118-120 °C/20 mmHg (lit.)
Density  1.11 g/mL at 25 °C (lit.)
refractive index  1.5302 (rough estimate)
Flash point: 118-120°C/20mm
storage temp.  -20°C
pka 11.43±0.70(Predicted)
form  powder to crystal
color  White to Light yellow
Water Solubility  slightly soluble
Sensitive  Air & Moisture Sensitive
BRN  1562059
CAS DataBase Reference 613-91-2(CAS DataBase Reference)
NIST Chemistry Reference Ethanone, 1-phenyl-, oxime(613-91-2)
EPA Substance Registry System Ethanone, 1-phenyl-, oxime (613-91-2)

Safety information for Acetophenone oxime

Signal word Danger
Pictogram(s)
ghs
Corrosion
Corrosives
GHS05
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H302:Acute toxicity,oral
H318:Serious eye damage/eye irritation
Precautionary Statement Codes P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P270:Do not eat, drink or smoke when using this product.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P330:Rinse mouth.
P501:Dispose of contents/container to..…

Computed Descriptors for Acetophenone oxime

InChIKey JHNRZXQVBKRYKN-CLFYSBASSA-N

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