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HomeProduct name list9-Bromophenanthrene

9-Bromophenanthrene

  • CAS NO.:573-17-1
  • Empirical Formula: C14H9Br
  • Molecular Weight: 257.13
  • MDL number: MFCD00001174
  • EINECS: 209-351-6
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-12-04 20:40:58
9-Bromophenanthrene Structural

What is 9-Bromophenanthrene?

Description

9-Bromophenanthrene is a luminescent material that fluoresces at short wavelengths and can be used as a molecular probe to detect the presence of other compounds and the mechanism of reaction, among other things.

Chemical properties

light yellow powder. soluble in toluene, and chloroform (50 mg/ml).

The Uses of 9-Bromophenanthrene

9-Bromophenanthrene is used as halogenated building block. Isotope labelled 9-Bromophenanthrene (B687200), a halogenated polycyclic aromatic hydrocarbon that has been seen to have a room temperature phosphorescence that can be induced by β-cyclodextrin (β-CD) in the presence of cyclohexane; however, trace Fe(III) causes a decrease of the RTP emission.

Preparation

9-Bromophenanthrene (90-94%) is produced by adding bromine to a refluxing solution of phenanthrene in carbon tetrachloride. This is the starting-point of 9-substituted phenanthrenes, e.g, when heated with cuprous cyanide at 260℃, 9-bromophenanthrene forms the corresponding cyano-compound; this may be hydrolysed to phenanthrene-9-carboxylic acid. Phenanthrene undergoes the Friedel-Crafts reaction mainly in the 3-, and to a small extent, in the 2-position. It is chloromethylated in the 9-position. When nitrated, phenanthrene gives a mixture of three mononitro-derivatives, the 3-isomer predominating. Sulphonation of phenanthrene gives a mixture of 1-, 2-, 3- and 9-phenanthrenesulphonic acids, and the ratio of these isomers depends on the temperature.

Properties of 9-Bromophenanthrene

Melting point: 60-64 °C (lit.)
Boiling point: 180-190 °C/2 mmHg (lit.)
Density  1.4251 (rough estimate)
refractive index  1.6404 (estimate)
Flash point: >230 °F
storage temp.  Sealed in dry,Room Temperature
solubility  chloroform: 50 mg/mL, clear
form  Powder
color  Light yellow
BRN  1869927
InChI InChI=1S/C14H9Br/c15-14-9-10-5-1-2-6-11(10)12-7-3-4-8-13(12)14/h1-9H
CAS DataBase Reference 573-17-1(CAS DataBase Reference)
NIST Chemistry Reference Phenanthrene, 9-bromo-(573-17-1)

Safety information for 9-Bromophenanthrene

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for 9-Bromophenanthrene

InChIKey RSQXKVWKJVUZDG-UHFFFAOYSA-N
SMILES C1=C2C(C3C(C(Br)=C2)=CC=CC=3)=CC=C1

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