6-METHOXY-2-NAPHTHALENEBORONIC ACID
Synonym(s):6-Methoxy-2-naphthalenylboronic acid;6-Methoxy-2-naphthylboronic acid;6-Methoxynaphthalene-2-boronic acid
- CAS NO.:156641-98-4
- Empirical Formula: C11H11BO3
- Molecular Weight: 202.01
- MDL number: MFCD03093087
- EINECS: 627-194-5
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-05-15 10:43:20
What is 6-METHOXY-2-NAPHTHALENEBORONIC ACID?
Chemical properties
White to off-white crystalline powder
The Uses of 6-METHOXY-2-NAPHTHALENEBORONIC ACID
suzuki reaction
The Uses of 6-METHOXY-2-NAPHTHALENEBORONIC ACID
Reactant for:
- Suzuki-Miyaura coupling
- Enantioselective a-arylation of carbonyls via copper-bisoxazoline catalysis
- Enantioselective synthesis of aryl ketones
- Copper-catalyzed trifluoromethylation
- Rhodium-catalyzed oxidative coupling with alkynes
General Description
Contains varying amounts of anhydride.
Properties of 6-METHOXY-2-NAPHTHALENEBORONIC ACID
Melting point: | >295 °C(lit.) |
Boiling point: | 416.2±37.0 °C(Predicted) |
Density | 1.23±0.1 g/cm3(Predicted) |
storage temp. | Inert atmosphere,Room Temperature |
solubility | DMSO (Slightly), Methanol (Slightly, Heated) |
pka | 8.72±0.30(Predicted) |
form | powder to crystal |
color | White to Orange to Green |
BRN | 7636998 |
CAS DataBase Reference | 156641-98-4(CAS DataBase Reference) |
Safety information for 6-METHOXY-2-NAPHTHALENEBORONIC ACID
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P304+P340:IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P405:Store locked up. |
Computed Descriptors for 6-METHOXY-2-NAPHTHALENEBORONIC ACID
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6-(BENZYLOXY)-2-NAPHTHYLBORONIC ACID
6-PENTYLOXYNAPHTHALENE-2-BORONIC ACID
6-(TETRAHYDRO-2H-PYRAN-2-YLOXY)-2-NAPHTHYLBORONIC ACID
6-METHOXY-2-NAPHTHALENEBORONIC ACID
6-Ethoxy-2-naphthaleneboronic acid
2-(6-Benzyloxynaphthalen-2-yl)-5,5-dimethyl-1,3,2-dioxaborinane
2-(6-METHOXY-2-NAPHTHYL)-5,5-DIMETHYL-1,3,2-DIOXABORINANE
2-(6-Methoxynaphthalen-2-yl)-4,4,6-trimethyl-1,3,2-dioxaborinane
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