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HomeProduct name list6-BROMO-1,4-BENZODIOXANE

6-BROMO-1,4-BENZODIOXANE

  • CAS NO.:52287-51-1
  • Empirical Formula: C8H7BrO2
  • Molecular Weight: 215.04
  • MDL number: MFCD00040750
  • EINECS: 257-817-2
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-04-23 13:52:06
6-BROMO-1,4-BENZODIOXANE Structural

What is 6-BROMO-1,4-BENZODIOXANE?

Chemical properties

Colorless liquid

The Uses of 6-BROMO-1,4-BENZODIOXANE

6-Bromo-1,4-benzodioxane may be used as a starting reagent in the synthesis of chiral diphosphines (SYNPHOS and DIFLUORPHOS).

General Description

6-Bromo-1,4-benzodioxane is an aryl halide. It can be synthesized from 1,4-benzodioxane, via bromination with bromine in acetic acid. It undergoes alkoxycarbonylation reaction with sodium tert-butoxide in the presence of CO to yield 2,3-dihydro-benzo[1,4]dioxine-6-carboxylic acid t-butyl ester.

Properties of 6-BROMO-1,4-BENZODIOXANE

Boiling point: 259-260 °C(lit.)
Density  1.598 g/mL at 25 °C(lit.)
refractive index  n20/D 1.588(lit.)
Flash point: >230 °F
storage temp.  Sealed in dry,Room Temperature
form  Liquid
color  Colorless to pale yellow
Specific Gravity 1.598
BRN  6223
CAS DataBase Reference 52287-51-1(CAS DataBase Reference)

Safety information for 6-BROMO-1,4-BENZODIOXANE

Signal word Danger
Pictogram(s)
ghs
Skull and Crossbones
Acute Toxicity
GHS06
ghs
Health Hazard
GHS08
ghs
Environment
GHS09
GHS Hazard Statements H360:Reproductive toxicity
H410:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P201:Obtain special instructions before use.
P202:Do not handle until all safety precautions have been read and understood.
P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P270:Do not eat, drink or smoke when using this product.
P271:Use only outdoors or in a well-ventilated area.
P273:Avoid release to the environment.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P391:Collect spillage. Hazardous to the aquatic environment
P308+P313:IF exposed or concerned: Get medical advice/attention.
P405:Store locked up.
P403+P233:Store in a well-ventilated place. Keep container tightly closed.

Computed Descriptors for 6-BROMO-1,4-BENZODIOXANE

InChIKey LFCURAJBHDNUNG-UHFFFAOYSA-N

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