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HomeProduct name list4,4'-Thiobis(6-tert-butyl-m-cresol)

4,4'-Thiobis(6-tert-butyl-m-cresol)

Synonym(s):4,4′-Thiobis(2-tert-butyl-5-methylphenol);5-tert-Butyl-4-hydroxy-2-methylphenyl sulfide;Bis(3-tert-butyl-4-hydroxy-6-methylphenyl)sulfide

  • CAS NO.:96-69-5
  • Empirical Formula: C22H30O2S
  • Molecular Weight: 358.54
  • MDL number: MFCD00026287
  • EINECS: 202-525-2
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-12-18 13:37:16
4,4'-Thiobis(6-tert-butyl-m-cresol) Structural

What is 4,4'-Thiobis(6-tert-butyl-m-cresol)?

Chemical properties

white to almost white crystals or crystalline

Chemical properties

4,40-Thiobis(6-tert-butyl-m-cresol) is a light gray to tan powder. Aromatic odor.

The Uses of 4,4'-Thiobis(6-tert-butyl-m-cresol)

Protection of light-colored rubber from oxidation and of nonstaining neoprene compounds against deterioration.

The Uses of 4,4'-Thiobis(6-tert-butyl-m-cresol)

As an antioxidant in the rubber and plastics industry; as a stabilizer in polyethylene and polyolefin packaging materials for foodstuffs.

The Uses of 4,4'-Thiobis(6-tert-butyl-m-cresol)

4,4''-Thiobis(2-tert-butyl-5-methylphenol) is an antioxidant. 4,4''-Thiobis(2-tert-butyl-5-methylphenol) is a radical inhibitor which prevented thermal decomposition of the peracid.

General Description

White or light gray to tan powder.

Air & Water Reactions

Sensitive to base hydrolysis and may spontaneously oxidize in solution. . Insoluble in water.

Reactivity Profile

4,4'-Thiobis(6-tert-butyl-m-cresol) may be sensitive to light.

Hazard

Toxic by inhalation. Upper respiratory tract irritant. Questionable carcinogen.

Health Hazard

4,4'-Thiobis(6-tert-butyl-mcresol) (TBBC) is of low systemic toxicity in animals; allergic contact dermatitis has been reported in humans.

Fire Hazard

4,4'-Thiobis(6-tert-butyl-m-cresol) is combustible.

Flammability and Explosibility

Non flammable

Safety Profile

Poison by intraperitoneal route and probably by ingestion and inhalation. Mutation data reported. See also SULFIDES. When heated to decomposition it emits highly toxic fumes of SOx.

Potential Exposure

This material is used as an antioxidant in the plastics and rubber industries; in Neoprene and other synthetic rubbers; in polyethylene and polypropylene.

Carcinogenicity

TBBC was not mutagenic in Salmonella typhimurium strains with or without metabolic activation. In Chinese hamster ovary cells, TBBC induced an increase in sister chromatid exchanges but there were no increases in chromosomal aberrations.

Incompatibilities

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. May evolve explosive hydrogen sulfide upon contact with moisture or acids.

Properties of 4,4'-Thiobis(6-tert-butyl-m-cresol)

Melting point: 160-165 °C
Boiling point: 460.94°C (rough estimate)
Density  1.06~1.12g/cm3
vapor pressure  0.001Pa at 20℃
refractive index  1.5200 (estimate)
Flash point: 215 °C
storage temp.  Store below +30°C.
solubility  DMSO (Slightly), Methanol (Slightly)
pka 10.76±0.36(Predicted)
form  Fine white to gray powder.
color  White to Off-White
Water Solubility  <0.01 g/100 mL at 18 ºC
Stability: Stable under recommended storage conditions., Stable Under Recommended Storage C
CAS DataBase Reference 96-69-5(CAS DataBase Reference)
NIST Chemistry Reference 4,4'-Thiobis(3-methyl-6-t-butylphenol)(96-69-5)
EPA Substance Registry System 4,4'-Thiobis(6-tert-butyl-m-cresol) (96-69-5)

Safety information for 4,4'-Thiobis(6-tert-butyl-m-cresol)

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
ghs
Environment
GHS09
GHS Hazard Statements H317:Sensitisation, Skin
H410:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P272:Contaminated work clothing should not be allowed out of the workplace.
P273:Avoid release to the environment.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P333+P313:IF SKIN irritation or rash occurs: Get medical advice/attention.

Computed Descriptors for 4,4'-Thiobis(6-tert-butyl-m-cresol)

InChIKey HXIQYSLFEXIOAV-UHFFFAOYSA-N

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