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HomeProduct name list4,4-DIMETHYL-2-PHENYL-2-OXAZOLINE

4,4-DIMETHYL-2-PHENYL-2-OXAZOLINE

4,4-DIMETHYL-2-PHENYL-2-OXAZOLINE Structural

What is 4,4-DIMETHYL-2-PHENYL-2-OXAZOLINE?

The Uses of 4,4-DIMETHYL-2-PHENYL-2-OXAZOLINE

4,4-Dimethyl-2-phenyl-2-oxazoline may be used in the synthesis of an ester-ammonium salt via rupture of oxazoline ring.

Synthesis Reference(s)

Journal of the American Chemical Society, 82, p. 2032, 1960 DOI: 10.1021/ja01493a045
Tetrahedron Letters, 27, p. 5269, 1986 DOI: 10.1016/S0040-4039(00)85187-4

General Description

4,4-Dimethyl-2-phenyl-2-oxazoline is an 2-aryl-2-oxazoline and has been tested as as ligand for the Suzuki coupling reaction of aryl bromides and arylboronic acids. 4,4-Dimethyl-2-phenyl-2-oxazoline forms mildly hygroscopic complexes, of general formulae [ZnX2(ox)2] (ox =4,4-Dimethyl-2-phenyl-2-oxazoline), with ether solutions of [ZnX2] (X = Cl, Br, I).Except ZnI2, which does not form an isolable complex due to steric reasons.

Properties of 4,4-DIMETHYL-2-PHENYL-2-OXAZOLINE

Melting point: 20-24 °C(lit.)
Boiling point: 124 °C20 mm Hg(lit.)
Density  1.025 g/mL at 25 °C(lit.)
refractive index  n20/D 1.5322(lit.)
Flash point: 217 °F
pka 4.82±0.70(Predicted)
BRN  132225

Safety information for 4,4-DIMETHYL-2-PHENYL-2-OXAZOLINE

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P321:Specific treatment (see … on this label).
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P332+P313:IF SKIN irritation occurs: Get medical advice/attention.
P337+P313:IF eye irritation persists: Get medical advice/attention.

Computed Descriptors for 4,4-DIMETHYL-2-PHENYL-2-OXAZOLINE

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