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HomeProduct name list4-Morpholinecarbonyl chloride

4-Morpholinecarbonyl chloride

  • CAS NO.:15159-40-7
  • Empirical Formula: C5H8ClNO2
  • Molecular Weight: 149.58
  • MDL number: MFCD00037053
  • EINECS: 239-213-0
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-02-23 09:13:43
4-Morpholinecarbonyl chloride Structural

What is 4-Morpholinecarbonyl chloride?

The Uses of 4-Morpholinecarbonyl chloride

4-Morpholinecarbonyl chloride may be used in the preparation of a versatile fluorogenic label for biomolecular imaging. It may be used in the synthesis of:

  • morpholine-4-carboxylic acid [4-(2,4-dimethylphenyl)thiazol-2-yl]amide
  • morpholine-4-carboxylic acid [4-(2,4,6-trimethylphenyl)thiazol-2-yl]amide
  • 2-isopropyl-6-methylpyrimidin-4-yl morpholine-4-carboxylate

The Uses of 4-Morpholinecarbonyl chloride

Photographic intermediate

What are the applications of Application

4-Morpholinecarbonyl chloride is A photographic intermediate

General Description

4-Morpholinecarbonyl chloride is a photographic intermediate. Rates of solvolysis of 4-morpholinecarbonyl chloride with N-alkyl group in aqueous binary solvents of acetone, ethanol, methanol, methanol-d, 2,2,2-trifluoroethanol, pure water and D2O has been determined. Preparation of 4-morpholinecarbonyl chloride has been reported.

Synthesis

4-Morpholinecarbonyl chloride is prepared by reacting morpholine hydrochloride with phosgene in an inert liquid medium such as toluene and xylene, at 50W150°C, pref. 60W120°C. The morpholine hydrochloride is prepared by dissolving 1 part by weight of morpholine in ≥4 parts of an inert liquid medium and introducing a slightly excessive HCl into the solution under agitation.

Properties of 4-Morpholinecarbonyl chloride

Boiling point: 137-138 °C/33 mmHg (lit.)
Density  1.282 g/mL at 25 °C (lit.)
refractive index  n20/D 1.498(lit.)
Flash point: >230 °F
storage temp.  Inert atmosphere,2-8°C
form  clear liquid
pka -2.16±0.20(Predicted)
color  Colorless to Light yellow
BRN  116257
InChI InChI=1S/C5H8ClNO2/c6-5(8)7-1-3-9-4-2-7/h1-4H2
CAS DataBase Reference 15159-40-7(CAS DataBase Reference)
EPA Substance Registry System 4-Morpholinecarbonyl chloride (15159-40-7)

Safety information for 4-Morpholinecarbonyl chloride

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
ghs
Health Hazard
GHS08
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H351:Carcinogenicity
Precautionary Statement Codes P201:Obtain special instructions before use.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P308+P313:IF exposed or concerned: Get medical advice/attention.

Computed Descriptors for 4-Morpholinecarbonyl chloride

InChIKey XMWFMEYDRNJSOO-UHFFFAOYSA-N
SMILES C(Cl)(N1CCOCC1)=O

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