4-Iodotoluene
Synonym(s):1-Iodo-4-methylbenzene
- CAS NO.：624-31-7
- Empirical Formula: C7H7I
- Molecular Weight: 218.04
- MDL number: MFCD00001059
- EINECS: 210-841-7
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-08-24 19:19:26
What is 4-Iodotoluene?
Chemical properties
WHITE TO LIGHT YELLOW CRYSTALLINE LOW MELTING MASS
The Uses of 4-Iodotoluene
4-Iodotoluene is used in wide range of medicals industrial applications as well as in pharmaceutical intermediates, polarizing films for Liquid Crystal Display (LCD) chemicals.
The Uses of 4-Iodotoluene
suzuki reaction
Synthesis Reference(s)
The Journal of Organic Chemistry, 52, p. 691, 1987 DOI: 10.1021/jo00380a041
Synthesis, p. 572, 1980 DOI: 10.1055/s-1980-29128
General Description
4-Iodotoluene undergoes Suzuki-Miyaura coupling reaction with phenylboronic acid catalyzed by (Ni,Mg)3Si2O5(OH)4 solid-solution nanotubes loaded with palladium. Cobalt-catalyzed coupling of 4-iodotoluene with thiophenols and alkanethiols has been investigated. Palladium/copper-catalyzed Sonogashira cross-coupling reaction of 4-iodotoluene with phenylacetylene has been studied.
Purification Methods
Crystallise 4-iodotoluene from EtOH and.or distil it. [Beilstein 5 IV 840.]
Properties of 4-Iodotoluene
| Melting point: | 33-35 °C (lit.) |
| Boiling point: | 211.5 °C (lit.) |
| Density | 1,678 g/cm3 |
| refractive index | 1.6155 (estimate) |
| Flash point: | 194 °F |
| storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
| solubility | Solubility in methanol is almost transparent. |
| form | Crystalline Low Melting Mass |
| color | White to light yellow |
| Water Solubility | insoluble |
| Sensitive | Light Sensitive |
| BRN | 1903637 |
| CAS DataBase Reference | 624-31-7(CAS DataBase Reference) |
| NIST Chemistry Reference | Benzene, 1-iodo-4-methyl-(624-31-7) |
| EPA Substance Registry System | Benzene, 1-iodo-4-methyl- (624-31-7) |
Safety information for 4-Iodotoluene
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for 4-Iodotoluene
| InChIKey | UDHAWRUAECEBHC-UHFFFAOYSA-N |
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