4-Bromobiphenyl
- CAS NO.:92-66-0
- Empirical Formula: C12H9Br
- Molecular Weight: 233.1
- MDL number: MFCD00000100
- EINECS: 202-176-6
- Update Date: 2024-10-24 21:11:45
What is 4-Bromobiphenyl?
Chemical properties
White powder
The Uses of 4-Bromobiphenyl
4-Bromobiphenyl is used as halogenated hydrocarbon and Intermediates of Liquid Crystals. It is also used in used in the synthesis of 4-biphenylthiolate.
The Uses of 4-Bromobiphenyl
4-Bromobiphenyl is used as a reagent in the synthesis of spirooxindole derivatives for use as AMPK activators. It is also used as a reagent in the preparation of indenoindole derivatives as organic electroluminescent device materials.
What are the applications of Application
4-Bromobiphenyl is a halogenated hydrocarbon
General Description
Colorless crystals. Insoluble in water.
Air & Water Reactions
Insoluble in water.
Reactivity Profile
4-Bromobiphenyl may be sensitive to light, and it can react with oxidizing materials.
Fire Hazard
Combustible.
Synthesis
Into a 250 ml reactor equipped with magnetic agitation means, a condenser, a dropping funnel, and a thermometer, the following materials were introduced:
(i) 15.4 g biphenyl (0.1 M);
(ii) 100 ml solvent
at ambient temperature Then, over 10 min, the bromine was poured therein (39.2 g/0.22 M), whereupon the mixture was agitated for a varying period of time at ambient temperature. Upon completion of the reaction, the excess bromine was consumed by sodium or potassium sulfite or bisulfite. The organic phase was washed, dried and diluted to a given volume, and analyzed by CPG to give 4-Bromobiphenyl.
Purification Methods
Crystallise the biphenyl from abolute EtOH and dry it in vacuo.[Beilstein 5 IV 1819.]
Properties of 4-Bromobiphenyl
Melting point: | 82-86 °C(lit.) |
Boiling point: | 310 °C(lit.) |
Density | 0.9327 |
refractive index | 1.6565 (estimate) |
Flash point: | 143 °C |
storage temp. | Sealed in dry,Room Temperature |
solubility | dioxane: soluble1g/10 mL, clear, colorless to very faintly yellow |
form | Crystalline Flakes |
color | Almost white to slightly yellow |
Water Solubility | Insoluble |
BRN | 1907453 |
Stability: | Stable. Incompatible with oxidizing agents. |
CAS DataBase Reference | 92-66-0(CAS DataBase Reference) |
NIST Chemistry Reference | 1,1'-Biphenyl, 4-bromo-(92-66-0) |
EPA Substance Registry System | 4-Bromobiphenyl (92-66-0) |
Safety information for 4-Bromobiphenyl
Signal word | Danger |
Pictogram(s) |
Corrosion Corrosives GHS05 Exclamation Mark Irritant GHS07 Environment GHS09 |
GHS Hazard Statements |
H302:Acute toxicity,oral H315:Skin corrosion/irritation H318:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation H400:Hazardous to the aquatic environment, acute hazard |
Precautionary Statement Codes |
P273:Avoid release to the environment. P280:Wear protective gloves/protective clothing/eye protection/face protection. P391:Collect spillage. Hazardous to the aquatic environment |
Computed Descriptors for 4-Bromobiphenyl
InChIKey | PKJBWOWQJHHAHG-UHFFFAOYSA-N |
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