3,4-METHYLENEDIOXYPHENYLBORONIC ACID
Synonym(s):1,3-Benzodioxole-5-boronic acid
- CAS NO.：94839-07-3
- Empirical Formula: C7H7BO4
- Molecular Weight: 165.94
- MDL number: MFCD01009695
- EINECS: 672-307-3
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-04-23 13:52:06
What is 3,4-METHYLENEDIOXYPHENYLBORONIC ACID?
Chemical properties
3,4-METHYLENEDIOXYPHENYLBORONIC ACID is white powder
The Uses of 3,4-METHYLENEDIOXYPHENYLBORONIC ACID
Reactant involved in:• ;Petasis reaction between glyoxylic acid, α-amino phosphonates, and organylboronic acids1• ;Mannich-type multicomponent assembly and 1,3-dipolar cycloaddition for synthesis of tetrahydroisoquinoline fused isoxazolidine scafford2• ;Suzuki-Miyaura cross-coupling of aryl and heteroaryl halides3,4• ;Oxidative Heck reaction for synthesis of functionalized cinnamaldehyde derivatives5• ;Intramolecular Alder-ene and Pictet-Spengler reactions for synthesis of crinine6
The Uses of 3,4-METHYLENEDIOXYPHENYLBORONIC ACID
suzuki reaction
The Uses of 3,4-METHYLENEDIOXYPHENYLBORONIC ACID
Reactant involved in:
- Petasis reaction between glyoxylic acid, α-amino phosphonates, and organylboronic acids
- Mannich-type multicomponent assembly and 1,3-dipolar cycloaddition for synthesis of tetrahydroisoquinoline fused isoxazolidine scafford
- Suzuki-Miyaura cross-coupling of aryl and heteroaryl halides
- Oxidative Heck reaction for synthesis of functionalized cinnamaldehyde derivatives
- Intramolecular Alder-ene and Pictet-Spengler reactions for synthesis of crinine
Properties of 3,4-METHYLENEDIOXYPHENYLBORONIC ACID
| Melting point: | 224-229 °C(lit.) |
| Boiling point: | 347.3±52.0 °C(Predicted) |
| Density | 1.42±0.1 g/cm3(Predicted) |
| storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
| form | Powder |
| pka | 8.48±0.20(Predicted) |
| color | White to off-white |
| BRN | 5523347 |
| CAS DataBase Reference | 94839-07-3(CAS DataBase Reference) |
Safety information for 3,4-METHYLENEDIOXYPHENYLBORONIC ACID
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P280:Wear protective gloves/protective clothing/eye protection/face protection. P304+P340:IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P405:Store locked up. |
Computed Descriptors for 3,4-METHYLENEDIOXYPHENYLBORONIC ACID
| InChIKey | CMHPUBKZZPSUIQ-UHFFFAOYSA-N |
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