3-VINYLPHENYLBORONIC ACID
Synonym(s):(3-Ethenylphenyl)boronic acid;m-Vinylbenzeneboronic acid
- CAS NO.:15016-43-0
- Empirical Formula: C8H9BO2
- Molecular Weight: 147.97
- MDL number: MFCD01074679
- EINECS: 604-722-2
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-01-05 11:48:35
What is 3-VINYLPHENYLBORONIC ACID?
The Uses of 3-VINYLPHENYLBORONIC ACID
suzuki reaction
The Uses of 3-VINYLPHENYLBORONIC ACID
Reactant involved in:
- Suzuki-Miyaura reactions
- Molecular imprinting of fructose and pinacol
- Synthesis of arylmercapturic acids via Chen-Lam-Evans arylation
- Three-component cross-coupling yeilding diarylketones
- Generation of acyl anion equivalents
General Description
May contain varying amounts of anhydride.
Purification Methods
This binder for paper or glass crystallises in white plates from H2O (m 144-145o), and its IR has max 919 and 995 (CH2CH=CH2), 1350 (B-O) and 3220 (OH) cm-1 . The dibromo derivative crystallises in white needles from H2O with m 196-197.5o. [Wesley & Rush J Org Chem 27 2598 1962, Beilstein 16 III 1279, 16 IV 1677.]
Properties of 3-VINYLPHENYLBORONIC ACID
Melting point: | 141-147 °C |
Boiling point: | 320.2±35.0 °C(Predicted) |
Density | 1.09±0.1 g/cm3(Predicted) |
storage temp. | 2-8°C |
form | powder or crystals |
pka | 8.34±0.10(Predicted) |
BRN | 3030426 |
CAS DataBase Reference | 15016-43-0(CAS DataBase Reference) |
Safety information for 3-VINYLPHENYLBORONIC ACID
Signal word | Danger |
Pictogram(s) |
Skull and Crossbones Acute Toxicity GHS06 Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H301:Acute toxicity,oral H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P280:Wear protective gloves/protective clothing/eye protection/face protection. P301+P310:IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P304+P340:IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P405:Store locked up. |
Computed Descriptors for 3-VINYLPHENYLBORONIC ACID
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[3-(E-3-METHOXY-3-OXO-1-PROPEN-1-YL)PHENYL]BORONIC ACID
3-[(E)-2-NITROVINYL]PHENYLBORONIC ACID
3-(3-BORONOPHENYL)ACRYLONITRILE
3-VINYLPHENYLBORONIC ACID
3-(2,2-Dicyanovinyl)phenylboronic acid
3-((E)-3-ETHOXY-3-OXO-1-PROPEN-1-YL)BENZENEBORONIC ACID 98
Benzocyclobutene-4-boronic acid
3-(2-CARBOXYVINYL)BENZENEBORONIC ACID
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