3-Chloro-4-fluoronitrobenzene
Synonym(s):2-Chloro-1-fluoro-4-nitrobenzene
- CAS NO.：350-30-1
- Empirical Formula: C6H3ClFNO2
- Molecular Weight: 175.54
- MDL number: MFCD00007206
- EINECS: 206-499-3
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-12-25 17:47:29
What is 3-Chloro-4-fluoronitrobenzene?
Chemical properties
white to light yellow crystal powder
The Uses of 3-Chloro-4-fluoronitrobenzene
2-Chloro-1-fluoro-4-nitrobenzene is an intermediate used in synthesis of benzoimidolones on Ameba resin and methyl 6,7,8,9-tetrahydropyrido[1,2-a]indol-10-ylacetate.
The Uses of 3-Chloro-4-fluoronitrobenzene
2-Chloro-1-fluoro-4-nitrobenzene has been used in synthesis of:
- benzoimidolones on Ameba resin
- methyl 6,7,8,9-tetrahydropyrido[1,2-a]indol-10-ylacetate
Synthesis Reference(s)
The Journal of Organic Chemistry, 63, p. 8448, 1998 DOI: 10.1021/jo981557o
Synthetic Communications, 21, p. 505, 1991 DOI: 10.1080/00397919108016776
General Description
2-Chloro-1-fluoro-4-nitrobenzene undergoes reduction in the presence of Mo(CO)6 and 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) under microwave irradiation to yield a mixture of 3-chloro-4-fluoroaniline and 3-chloro-4-ethoxyaniline.
Properties of 3-Chloro-4-fluoronitrobenzene
| Melting point: | 40-42 °C(lit.) |
| Boiling point: | 227-232°C |
| Density | 1.61 |
| Flash point: | >230 °F |
| storage temp. | Sealed in dry,Room Temperature |
| solubility | soluble in Methanol |
| form | powder to crystal |
| color | White to Light yellow to Green |
| BRN | 1944997 |
| CAS DataBase Reference | 350-30-1(CAS DataBase Reference) |
| NIST Chemistry Reference | 3-Chloro-4-fluoronitrobenzene(350-30-1) |
| EPA Substance Registry System | 3-Chloro-4-fluoronitrobenzene (350-30-1) |
Safety information for 3-Chloro-4-fluoronitrobenzene
| Signal word | Danger |
| Pictogram(s) |
 Corrosion Corrosives GHS05  Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H302:Acute toxicity,oral H315:Skin corrosion/irritation H318:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P280:Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for 3-Chloro-4-fluoronitrobenzene
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