3-Bromoquinoline
- CAS NO.：5332-24-1
- Empirical Formula: C9H6BrN
- Molecular Weight: 208.05
- MDL number: MFCD00006767
- EINECS: 226-237-1
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-12-14 20:49:34
What is 3-Bromoquinoline?
Chemical properties
colorless to light yellow liquid
Synthesis Reference(s)
The Journal of Organic Chemistry, 27, p. 1318, 1962 DOI: 10.1021/jo01051a047
General Description
3-Bromoquinoline undergoes bromine-magnesium exchange reaction with lithium tributylmagnesate in toluene at -10°C, which is quenched by various electrophiles to yield functionalized quinolines.
Flammability and Explosibility
Not classified
Properties of 3-Bromoquinoline
| Melting point: | 13-15 °C (lit.) |
| Boiling point: | 274-276 °C (lit.) |
| Density | 1.533 g/mL at 25 °C (lit.) |
| vapor pressure | 0.196Pa at 25℃ |
| refractive index | n |
| Flash point: | >230 °F |
| storage temp. | Keep in dark place,Inert atmosphere,Room temperature |
| pka | 2.69(at 25℃) |
| form | Liquid |
| color | Clear colorless to yellow |
| Water Solubility | 103mg/L at 25℃ |
| BRN | 112939 |
| CAS DataBase Reference | 5332-24-1(CAS DataBase Reference) |
| NIST Chemistry Reference | Quinoline, 3-bromo-(5332-24-1) |
| EPA Substance Registry System | Quinoline, 3-bromo- (5332-24-1) |
Safety information for 3-Bromoquinoline
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for 3-Bromoquinoline
| InChIKey | ZGIKWINFUGEQEO-UHFFFAOYSA-N |
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