(2S)-(+)-GLYCIDYL 4-NITROBENZOATE
- CAS NO.：115459-65-9
- Empirical Formula: C10H9NO5
- Molecular Weight: 223.18
- MDL number: MFCD00064490
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-06-29 08:28:13
What is (2S)-(+)-GLYCIDYL 4-NITROBENZOATE?
Purification Methods
Purify glycidol by fractional distillation.The 4-nitrobenzoates have m 56o (±); m 60-62o, [] D 20 -37.9o (c 3.38 CHCl3) for R-(-)-isomer [106268-95-5];m 60-62o, [] D 20 +38o (c 1 CHCl3) for the S-(+)-isomer [115459-65-9] and are recrystallised from Et2O or Et2O/pet ether (b 40-60o) [S-isomer: Burgos et al. J Org Chem 52 4973 1987, Sowden & Fischer J Am Chem Soc 64 1291 1942.] [Beilstein 17 I 50, 17 III/IV 985, 17/3 V 9.] Gramine.
Properties of (2S)-(+)-GLYCIDYL 4-NITROBENZOATE
| Melting point: | 60-62 °C (lit.) |
| storage temp. | 2-8°C |
| optical activity | [α]19/D +37°, c = 1.08 in chloroform |
| BRN | 87687 |
Safety information for (2S)-(+)-GLYCIDYL 4-NITROBENZOATE
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for (2S)-(+)-GLYCIDYL 4-NITROBENZOATE
New Products
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