(2R)-(-)-GLYCIDYL 4-NITROBENZOATE
Synonym(s):(R)-(−)-Glycidyl 4-nitrobenzoate;(R)-(−)-Oxirane-2-methanol 4-nitrobenzoate
- CAS NO.：106268-95-5
- Empirical Formula: C10H9NO5
- Molecular Weight: 223.18
- MDL number: MFCD00010835
- SAFETY DATA SHEET (SDS)
- Update Date: 2022-12-21 16:56:50
What is (2R)-(-)-GLYCIDYL 4-NITROBENZOATE?
The Uses of (2R)-(-)-GLYCIDYL 4-NITROBENZOATE
(2R)-(?)-Glycidyl 4-nitrobenzoate can be used as a starting material in the total synthesis of leukotriene B4.
Purification Methods
Purify glycidol by fractional distillation.The 4-nitrobenzoates have m 56o (±); m 60-62o, [] D20 -37.9o (c 3.38 CHCl3) for R-(-)-isomer [106268-95-5];m 60-62o, [] D20 +38o (c 1 CHCl3) for the S-(+)-isomer [115459-65-9] and are recrystallised from Et2O or Et2O/pet ether (b 40-60o) [S-isomer: Burgos et al. J Org Chem 52 4973 1987, Sowden & Fischer J Am Chem Soc 64 1291 1942.] [Beilstein 17 I 50, 17 III/IV 985, 17/3 V 9.]
Properties of (2R)-(-)-GLYCIDYL 4-NITROBENZOATE
| Melting point: | 60-62 °C (lit.) |
| storage temp. | 2-8°C |
| optical activity | [α]19/D 37°, c = 1.08 in chloroform |
| BRN | 5278590 |
Safety information for (2R)-(-)-GLYCIDYL 4-NITROBENZOATE
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for (2R)-(-)-GLYCIDYL 4-NITROBENZOATE
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