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HomeProduct name list2,6-DI-TERT-BUTYLPYRIDINE

2,6-DI-TERT-BUTYLPYRIDINE

  • CAS NO.:585-48-8
  • Empirical Formula: C13H21N
  • Molecular Weight: 191.31
  • MDL number: MFCD00006306
  • EINECS: 209-557-6
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-08-12 17:17:06
2,6-DI-TERT-BUTYLPYRIDINE Structural

What is 2,6-DI-TERT-BUTYLPYRIDINE?

Chemical properties

dark brown liquid

The Uses of 2,6-DI-TERT-BUTYLPYRIDINE

2,6-Di-tert-butylpyridine is used in the preparation of 2, 6-di-tert-butylpyridine hydrotriflate. It is used as a proton scavenger to check the progress of the living polymerization of isobutylene. It is associated with cerric ammonium nitrate and used in the alfa-enolation of aldehydes. It is involved in the preparation of vinyl triflate using polymer-bound 2,6-di-tert-butylpyridine.

The Uses of 2,6-DI-TERT-BUTYLPYRIDINE

2,6-Di-tert-butylpyridine was used as proton trapping agent to investigate the living polymerization of isobutylene. It was also used with cerric ammonium nitrate in the α-enolation of aldehydes leading to 1,4-dicarbonyl systems.

Definition

ChEBI: 2,6-di-tert-butylpyridine is a member of pyridines.

What are the applications of Application

2,6-Di-tert-butylpyridine is a proton trap for living carbocationic polymerization

General Description

Reactivity of 2,6-di-tert-butylpyridine with iron(III) tetraphenylporphyrin pi-cation radical has been examined by proton NMR spectroscopy. Reaction of 2,6-di-tert-butylpyridine with methyl iodide and methyl fluorosulfonate under high pressure has been reported.

Purification Methods

Redistil it from KOH pellets. [Beilstein 20 III/IV 2868.]

Properties of 2,6-DI-TERT-BUTYLPYRIDINE

Melting point: 2°C(lit.)
Boiling point: 100-101 °C/23 mmHg (lit.)
Density  0.852 g/mL at 25 °C (lit.)
refractive index  1.472-1.474
Flash point: 72 °C
storage temp.  2-8°C
solubility  Chloroform (Slightly), Methanol (Slightly)
form  Liquid
pka 3.58(at 25℃)
Specific Gravity 0.852
color  Clear yellow
Water Solubility  Miscible with alcohol, acetone, and hexane. Immiscible with water.
Merck  14,3036
BRN  125886
Dielectric constant 3.3900000000000001
Stability: Stable. Combustible. Incompatible with strong acids, strong oxidizing agents.
CAS DataBase Reference 585-48-8(CAS DataBase Reference)

Safety information for 2,6-DI-TERT-BUTYLPYRIDINE

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P271:Use only outdoors or in a well-ventilated area.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for 2,6-DI-TERT-BUTYLPYRIDINE

InChIKey UWKQJZCTQGMHKD-UHFFFAOYSA-N

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