2,6-DI-TERT-BUTYLPYRIDINE
- CAS NO.:585-48-8
- Empirical Formula: C13H21N
- Molecular Weight: 191.31
- MDL number: MFCD00006306
- EINECS: 209-557-6
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-08-12 17:17:06
What is 2,6-DI-TERT-BUTYLPYRIDINE?
Chemical properties
dark brown liquid
The Uses of 2,6-DI-TERT-BUTYLPYRIDINE
2,6-Di-tert-butylpyridine is used in the preparation of 2, 6-di-tert-butylpyridine hydrotriflate. It is used as a proton scavenger to check the progress of the living polymerization of isobutylene. It is associated with cerric ammonium nitrate and used in the alfa-enolation of aldehydes. It is involved in the preparation of vinyl triflate using polymer-bound 2,6-di-tert-butylpyridine.
The Uses of 2,6-DI-TERT-BUTYLPYRIDINE
2,6-Di-tert-butylpyridine was used as proton trapping agent to investigate the living polymerization of isobutylene. It was also used with cerric ammonium nitrate in the α-enolation of aldehydes leading to 1,4-dicarbonyl systems.
Definition
ChEBI: 2,6-di-tert-butylpyridine is a member of pyridines.
What are the applications of Application
2,6-Di-tert-butylpyridine is a proton trap for living carbocationic polymerization
General Description
Reactivity of 2,6-di-tert-butylpyridine with iron(III) tetraphenylporphyrin pi-cation radical has been examined by proton NMR spectroscopy. Reaction of 2,6-di-tert-butylpyridine with methyl iodide and methyl fluorosulfonate under high pressure has been reported.
Purification Methods
Redistil it from KOH pellets. [Beilstein 20 III/IV 2868.]
Properties of 2,6-DI-TERT-BUTYLPYRIDINE
Melting point: | 2°C(lit.) |
Boiling point: | 100-101 °C/23 mmHg (lit.) |
Density | 0.852 g/mL at 25 °C (lit.) |
refractive index | 1.472-1.474 |
Flash point: | 72 °C |
storage temp. | 2-8°C |
solubility | Chloroform (Slightly), Methanol (Slightly) |
form | Liquid |
pka | 3.58(at 25℃) |
Specific Gravity | 0.852 |
color | Clear yellow |
Water Solubility | Miscible with alcohol, acetone, and hexane. Immiscible with water. |
Merck | 14,3036 |
BRN | 125886 |
Dielectric constant | 3.3900000000000001 |
Stability: | Stable. Combustible. Incompatible with strong acids, strong oxidizing agents. |
CAS DataBase Reference | 585-48-8(CAS DataBase Reference) |
Safety information for 2,6-DI-TERT-BUTYLPYRIDINE
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for 2,6-DI-TERT-BUTYLPYRIDINE
InChIKey | UWKQJZCTQGMHKD-UHFFFAOYSA-N |
New Products
4-Aminotetrahydropyran-4-carbonitrile Hydrochloride (R)-3-Aminobutanenitrile Hydrochloride 4-AMINO-TETRAHYDRO-PYRAN-4-CARBOXYLIC ACID HCL 4-(Dimethylamino)tetrahydro-2H-pyran-4-carbonitrile 3-((Dimethylamino)methyl)-5-methylhexan-2-one oxalate 1,4-Dioxa-8-azaspiro[4.5]decane 5-Bromo-2-nitropyridine Nimesulide BP Aceclofenac IP/BP/EP Mefenamic Acid IP/BP/EP/USP Diclofenac Sodium IP/BP/EP/USP Ornidazole IP Diclofenac Potassium SODIUM AAS SOLUTION ZINC AAS SOLUTION BUFFER SOLUTION PH 10.0(BORATE) GOOCH CRUCIBLE SINTERED AQUANIL 5 BERYLLIUM AAS SOLUTION 2-Bromo-1-(bromomethyl)-3-chloro-5-nitrobenzene 2-Bromo-3-nitroaniline N-(3-Hydroxypropyl)-N-methylacetamide 3-Bromo-6-chloropyridazine 4-ethyl-3-nitrobenzoic acidRelated products of tetrahydrofuran
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