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HomeProduct name list2,4,6-Triisopropylbenzene-sulfonyl azide

2,4,6-Triisopropylbenzene-sulfonyl azide

Synonym(s):2,4,6-Triisopropylphenylsulfonyl azide;2,4,6-Tris(1-methylethyl)-benzenesulfonyl azide;Trisyl azide solution

2,4,6-Triisopropylbenzene-sulfonyl azide Structural

What is 2,4,6-Triisopropylbenzene-sulfonyl azide?

Chemical properties

White wet solid

The Uses of 2,4,6-Triisopropylbenzene-sulfonyl azide

Reagent for:• ;Stereoselective diversity-oriented synthesis of functionalized saccharides1• ;Meyer′s lactamization2Reagent for synthesis of:• ;Antidote to anthrax lethal factor intoxication3• ;Bacterial RNA polymerase inhibitor4• ;Bicyclic extended dipeptide surrogates5• ;Single enantiomers of mycobacterial keomycolic acids6

The Uses of 2,4,6-Triisopropylbenzene-sulfonyl azide

2,4,6-Triisopropylbenzenesulfonyl azide is used as a reagent for diazo transfer to ketones, e.g. under phase-transfer conditions, giving better yields of sterically-hindered ?-diazo ketones than other methods. It is also used for azide transfer to potassium enolates (KHMDS) to form the ?-azido derivatives.

Properties of 2,4,6-Triisopropylbenzene-sulfonyl azide

Melting point: 39-44 °C
refractive index  n20/D1.499
Flash point: 4℃
storage temp.  2-8°C
solubility  Chloroform (Slightly), Ethyl Acetate (Slightly)
form  Solid
color  White to Off-White
Water Solubility  Insoluble in water.
BRN  2391566
CAS DataBase Reference 36982-84-0(CAS DataBase Reference)

Safety information for 2,4,6-Triisopropylbenzene-sulfonyl azide

Signal word Danger
Pictogram(s)
ghs
Flame
Flammables
GHS02
ghs
Exclamation Mark
Irritant
GHS07
ghs
Health Hazard
GHS08
GHS Hazard Statements H225:Flammable liquids
H302:Acute toxicity,oral
H304:Aspiration hazard
H315:Skin corrosion/irritation
H336:Specific target organ toxicity,single exposure; Narcotic effects
H373:Specific target organ toxicity, repeated exposure
H412:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P201:Obtain special instructions before use.
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P273:Avoid release to the environment.
P308+P313:IF exposed or concerned: Get medical advice/attention.

Computed Descriptors for 2,4,6-Triisopropylbenzene-sulfonyl azide

InChIKey AEMWUHCKKDPRSK-UHFFFAOYSA-N

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