2,4,6-Triisopropylbenzene-sulfonyl azide
Synonym(s):2,4,6-Triisopropylphenylsulfonyl azide;2,4,6-Tris(1-methylethyl)-benzenesulfonyl azide;Trisyl azide solution
- CAS NO.：36982-84-0
- Empirical Formula: C15H23N3O2S
- Molecular Weight: 309.43
- MDL number: MFCD00859286
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-05-15 10:43:51
What is 2,4,6-Triisopropylbenzene-sulfonyl azide?
Chemical properties
White wet solid
The Uses of 2,4,6-Triisopropylbenzene-sulfonyl azide
Reagent for:• ;Stereoselective diversity-oriented synthesis of functionalized saccharides1• ;Meyer′s lactamization2Reagent for synthesis of:• ;Antidote to anthrax lethal factor intoxication3• ;Bacterial RNA polymerase inhibitor4• ;Bicyclic extended dipeptide surrogates5• ;Single enantiomers of mycobacterial keomycolic acids6
The Uses of 2,4,6-Triisopropylbenzene-sulfonyl azide
2,4,6-Triisopropylbenzenesulfonyl azide is used as a reagent for diazo transfer to ketones, e.g. under phase-transfer conditions, giving better yields of sterically-hindered ?-diazo ketones than other methods. It is also used for azide transfer to potassium enolates (KHMDS) to form the ?-azido derivatives.
Properties of 2,4,6-Triisopropylbenzene-sulfonyl azide
| Melting point: | 39-44 °C |
| refractive index | n20/D1.499 |
| Flash point: | 4℃ |
| storage temp. | 2-8°C |
| solubility | Chloroform (Slightly), Ethyl Acetate (Slightly) |
| form | Solid |
| color | White to Off-White |
| Water Solubility | Insoluble in water. |
| BRN | 2391566 |
| CAS DataBase Reference | 36982-84-0(CAS DataBase Reference) |
Safety information for 2,4,6-Triisopropylbenzene-sulfonyl azide
| Signal word | Danger |
| Pictogram(s) |
 Flame Flammables GHS02  Exclamation Mark Irritant GHS07  Health Hazard GHS08 |
| GHS Hazard Statements |
H225:Flammable liquids H302:Acute toxicity,oral H304:Aspiration hazard H315:Skin corrosion/irritation H336:Specific target organ toxicity,single exposure; Narcotic effects H373:Specific target organ toxicity, repeated exposure H412:Hazardous to the aquatic environment, long-term hazard |
| Precautionary Statement Codes |
P201:Obtain special instructions before use. P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P273:Avoid release to the environment. P308+P313:IF exposed or concerned: Get medical advice/attention. |
Computed Descriptors for 2,4,6-Triisopropylbenzene-sulfonyl azide
| InChIKey | AEMWUHCKKDPRSK-UHFFFAOYSA-N |
Abamectin manufacturer
JSK Chemicals
1Y
Phone:+91 9879767970;+919879767970
Whatsapp: +91 9879767970
product: 36982-84-0 2,4,6-Triisopropylbenzenesulfonyl 99%
Innovative Labs
1Y
Phone:+91-9885794886
Whatsapp: +91-9885794886
product: 2,4,6-Triisopropylphenylsulfonyl azide 98%
New Products
(2S,4R)-4-amino-2-methyl-5-phenylpentanoic acid hydrochloride Tubulysin H Tubulysin M (R)-tert-butyl (4-methyl-1-oxopentan-3-yl)carbamate 1,2,3,6-TETRAHYDROPYRIDINE HYDROCHLORIDE 2,2-Difluoropropylamine hydrochloride 4-(Benzyloxy)-3-bromophenylacetic Acid 3-N-BOC-(S)-AMINO BUTYRONITRILE Isoxazole, 3-[[[5-(difluoromethoxy)-1-methyl-3-(trifluoromethyl)-1H-pyrazol-4-yl]methyl]thio]-4,5-dihydro-5,5-dimethyl- CYCLOBUTYLAMINE HYDROCHLORIDE 2-[[(3aR,4S,6R,6aS)-6-Aminotetrahydro-2,2-dimethyl-4H-cyclopenta-1,3-dioxol-4-yl]oxy]ethanol ethanedioate Calcium Sodium Phosphosilicate IH 2-(1-(Mercaptomethyl) cyclopropyl) acetonitrile Fuel shell Imeglimin Hydrochloride IH 2-[2-[3(S)-3[2-(7-chloro-2-quinolinyl) ethenyl] phenyl-3- hydroxyl propyl] phenyl]-2-propanol (+/-)-2, 6-Diamino-4,5,6,7 -tetrahydro Benzothiazole (3-Fluoro-4- morpholin-4-yl- phenyl)- carbamic acid methyl ester Lubiprostone Latanoprostene Bunod Magnesium Trisilicate Flame Retardant Zinc Borate 1H-Imidazole-4-carbonitrile 7-Methoxyquinoline-4-carbonitrileRelated products of tetrahydrofuran
You may like
-
36982-84-0 2,4,6-Triisopropylbenzenesulfonyl 99%View Details
36982-84-0 -
36982-84-0 98%View Details
36982-84-0 -
2,4,6-Triisopropylphenylsulfonyl azide 98%View Details
36982-84-0 -
2,4,6-Triisopropylbenzenesulfonyl Azide (wetted with ca. 10% Water) (unit weight on dry weight basis) CAS 36982-84-0View Details
36982-84-0 -
2,4,6-Triisopropylbenzenesulfonyl Azide CAS 36982-84-0View Details
36982-84-0 -
2,4,6-Triisopropylbenzenesulfonyl azide solution CAS 36982-84-0View Details
36982-84-0 -
4,6-dichloro-2-propylthiopyrimidine-5-amine 145783-15-9 98%View Details
145783-15-9 -
2-[2-[3(S)-3[2-(7-chloro-2-quinolinyl) ethenyl] phenyl-3- hydroxyl propyl] phenyl]-2-propanol 98%View Details
142569-70-8
Statement: All products displayed on this website are only used for non medical purposes such as industrial applications or scientific research, and cannot be used for clinical diagnosis or treatment of humans or animals. They are not medicinal or edible.