2,4,6-Triisopropylbenzene-sulfonyl azide
Synonym(s):2,4,6-Triisopropylphenylsulfonyl azide;2,4,6-Tris(1-methylethyl)-benzenesulfonyl azide;Trisyl azide solution
- CAS NO.:36982-84-0
- Empirical Formula: C15H23N3O2S
- Molecular Weight: 309.43
- MDL number: MFCD00859286
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-05-15 10:43:51
What is 2,4,6-Triisopropylbenzene-sulfonyl azide?
Chemical properties
White wet solid
The Uses of 2,4,6-Triisopropylbenzene-sulfonyl azide
Reagent for:• ;Stereoselective diversity-oriented synthesis of functionalized saccharides1• ;Meyer′s lactamization2Reagent for synthesis of:• ;Antidote to anthrax lethal factor intoxication3• ;Bacterial RNA polymerase inhibitor4• ;Bicyclic extended dipeptide surrogates5• ;Single enantiomers of mycobacterial keomycolic acids6
The Uses of 2,4,6-Triisopropylbenzene-sulfonyl azide
2,4,6-Triisopropylbenzenesulfonyl azide is used as a reagent for diazo transfer to ketones, e.g. under phase-transfer conditions, giving better yields of sterically-hindered ?-diazo ketones than other methods. It is also used for azide transfer to potassium enolates (KHMDS) to form the ?-azido derivatives.
Properties of 2,4,6-Triisopropylbenzene-sulfonyl azide
Melting point: | 39-44 °C |
refractive index | n20/D1.499 |
Flash point: | 4℃ |
storage temp. | 2-8°C |
solubility | Chloroform (Slightly), Ethyl Acetate (Slightly) |
form | Solid |
color | White to Off-White |
Water Solubility | Insoluble in water. |
BRN | 2391566 |
CAS DataBase Reference | 36982-84-0(CAS DataBase Reference) |
Safety information for 2,4,6-Triisopropylbenzene-sulfonyl azide
Signal word | Danger |
Pictogram(s) |
Flame Flammables GHS02 Exclamation Mark Irritant GHS07 Health Hazard GHS08 |
GHS Hazard Statements |
H225:Flammable liquids H302:Acute toxicity,oral H304:Aspiration hazard H315:Skin corrosion/irritation H336:Specific target organ toxicity,single exposure; Narcotic effects H373:Specific target organ toxicity, repeated exposure H412:Hazardous to the aquatic environment, long-term hazard |
Precautionary Statement Codes |
P201:Obtain special instructions before use. P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P273:Avoid release to the environment. P308+P313:IF exposed or concerned: Get medical advice/attention. |
Computed Descriptors for 2,4,6-Triisopropylbenzene-sulfonyl azide
InChIKey | AEMWUHCKKDPRSK-UHFFFAOYSA-N |
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