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HomeProduct name list2,4,6-Tribromoaniline

2,4,6-Tribromoaniline

  • CAS NO.:147-82-0
  • Empirical Formula: C6H4Br3N
  • Molecular Weight: 329.81
  • MDL number: MFCD00007634
  • EINECS: 205-700-1
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-09-19 18:11:18
2,4,6-Tribromoaniline Structural

What is 2,4,6-Tribromoaniline?

Chemical properties

BEIGE TO GREY CRYSTALLINE SOLID

The Uses of 2,4,6-Tribromoaniline

2,4,6-Tribromoaniline was used in simultaneous determination of phenolic brominated flame retardants and their by-products in water.

The Uses of 2,4,6-Tribromoaniline

A trihalogen substituted aniline with potential inhibitory effect on human cytochrome P 450 (CYP) 2E1.

Preparation

2,4,6-Tribromoaniline can be prepared by treating bromine water with aniline in a solution of acetic acid or dilute hydrochloric acid:
synthesis of 2,4,6-Tribromoaniline
synthesis-of-2-4-6-tribromoaniline-from-aniline

General Description

Electrochemical oxidation of 2,4,6-tribromoaniline in aqueous sulphuric acid solutions at platinum electrode has been studied by rotating disc electrode and cyclic voltammetry. 2,4,6-Tribromoaniline on closed-tube pyrolysis yields polybromophenazines. It is an intermediate in the formulation of flame retardants incorporated to plastic materials.

Purification Methods

Crystallise the aniline from MeOH. The benzenesulfonamide derivative has m 198o. [Beilstein 12 H 663, 12 I 329, 12 II 358, 12 III 1477, 12 IV 1538.]

Properties of 2,4,6-Tribromoaniline

Melting point: 120-122 °C(lit.)
Boiling point: 300 °C(lit.)
Density  2.35
refractive index  1.6890 (estimate)
Flash point: 300°C
solubility  alcohol: soluble (cold)(lit.)
form  powder to crystal
pka -0.23±0.10(Predicted)
color  White to Almost white
Merck  14,9610
BRN  2209258
CAS DataBase Reference 147-82-0(CAS DataBase Reference)
NIST Chemistry Reference Benzenamine, 2,4,6-tribromo-(147-82-0)
EPA Substance Registry System 2,4,6-Tribromoaniline (147-82-0)

Safety information for 2,4,6-Tribromoaniline

Signal word Danger
Pictogram(s)
ghs
Corrosion
Corrosives
GHS05
ghs
Skull and Crossbones
Acute Toxicity
GHS06
ghs
Health Hazard
GHS08
GHS Hazard Statements H301:Acute toxicity,oral
H311:Acute toxicity,dermal
H315:Skin corrosion/irritation
H318:Serious eye damage/eye irritation
H319:Serious eye damage/eye irritation
H332:Acute toxicity,inhalation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
H373:Specific target organ toxicity, repeated exposure
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P311:Call a POISON CENTER or doctor/physician.
P301+P310:IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405:Store locked up.

Computed Descriptors for 2,4,6-Tribromoaniline

InChIKey GVPODVKBTHCGFU-UHFFFAOYSA-N

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