2,2,6-TRIMETHYLCYCLOHEXANONE
- CAS NO.:2408-37-9
- Empirical Formula: C9H16O
- Molecular Weight: 140.22
- MDL number: MFCD00045550
- EINECS: 219-309-9
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-05-25 18:01:22
What is 2,2,6-TRIMETHYLCYCLOHEXANONE?
Chemical properties
CLEAR COLOURLESS LIQUID
Occurrence
Reported found in bilberries, passion fruit and tea. Also reported found in apricot, bilberry, white wine, black tea, green tea, microbial fermented tea, brewed tea, yellow passion fruit juice and dill herb.
The Uses of 2,2,6-TRIMETHYLCYCLOHEXANONE
2,2,6-Trimethylcyclohexanone is used as a flavoring agent. It is also used to prepare terpene viz. beta-ionone.
Aroma threshold values
Detection: 100 ppb; recognition: 310 ppb
Synthesis Reference(s)
Journal of the American Chemical Society, 80, p. 4072, 1958 DOI: 10.1021/ja01548a061
The Journal of Organic Chemistry, 27, p. 1615, 1962 DOI: 10.1021/jo01052a031
Purification Methods
Purify it via the semicarbazone (m 218o, from MeOH or EtOH), decompose this in the usual way (cf p 65 and 67, or MEK, p 106) and fractionally distil the liquid ketone through a vigreux column (p 11) at ~760mm. [Chakravarti J Chem Soc 1567 1947, Milas et al. J Am Chem Soc 70 1831 1948, Beilstein 7 I 24, 7 II 32, 7 III 7.]
Properties of 2,2,6-TRIMETHYLCYCLOHEXANONE
Melting point: | -31.8°C |
Boiling point: | 178-179 °C(lit.) |
Density | 0.904 g/mL at 25 °C(lit.) |
refractive index | n |
FEMA | 3473 | 2,2,6-TRIMETHYLCYCLOHEXANONE |
Flash point: | 125 °F |
storage temp. | Flammables area |
solubility | Chloroform (Slightly), Methanol (Slightly) |
form | Oil |
color | Colourless |
Specific Gravity | 0.904 |
Odor | at 10.00 % in dipropylene glycol. pungent thujone labdanum honey cistus |
Water Solubility | Slightly miscible with water. |
JECFA Number | 1108 |
BRN | 1905593 |
CAS DataBase Reference | 2408-37-9(CAS DataBase Reference) |
EPA Substance Registry System | 2,2,6-Trimethylcyclohexanone (2408-37-9) |
Safety information for 2,2,6-TRIMETHYLCYCLOHEXANONE
Pictogram(s) |
Flame Flammables GHS02 Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H226:Flammable liquids H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P405:Store locked up. |
Computed Descriptors for 2,2,6-TRIMETHYLCYCLOHEXANONE
Abamectin manufacturer
Neugen Labs
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