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HomeProduct name list2-Hydroxypropyl methacrylate

2-Hydroxypropyl methacrylate

  • CAS NO.:27813-02-1
  • Empirical Formula: C7H12O3
  • Molecular Weight: 144.17
  • MDL number: MFCD00004536
  • EINECS: 248-666-3
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-10-30 18:52:02
2-Hydroxypropyl methacrylate  Structural

What is 2-Hydroxypropyl methacrylate ?

Description

Hydroxypropyl methacrylate(HPMA) is a clear, colorless liquid with a pungent, sweet odor. The product contains low levels of a polymerization inhibitor along with small amounts of methacrylic acid, and propylene oxide. HPMA is used in the manufacture of acrylic polymers for adhesives, inks, and coatings for automotive, appliance and metal applications. The added hydroxyl groups improve adhesion to surfaces, incorporate cross-link sites, and impart corrosion, fogging, and abrasion resistance.

Chemical properties

Clear colorless liquid

The Uses of 2-Hydroxypropyl methacrylate

Monomer for acrylic resins, nonwoven fabric binders, detergent lubricating-oil additives.

The Uses of 2-Hydroxypropyl methacrylate

Hydroxypropyl methacrylate is a functional monomer for the preparation of hot solid acrylic coatings, styrene-butadiene latex modifiers, acrylic modified polyurethane coating ,water-soluble plating coatings , adhesives ,textile finishing agent ,paper coating , photosensitive paint and polyurethane vinyl resin modified agent. Mainly used in the manufacture are active groups of hydroxyl acrylic resin. Used in reactive diluent and cross-linking agent in the UV curing system.

What are the applications of Application

2-Hydroxypropyl Methacrylate (HPMA) used in the preparation of solid and emulsion polymers, acrylic dispersions in combination with other (meth) acrylates, which are used in various industries, especially for textile coatings and dressings. HPMA is widely used in the production of acrylic polyols for automotive components, refurbishment coatings, and industrial coatings. HPMA is also used as a comonomer in styrene-based unsaturated polyesters, PMMA-based acrylic resins, and vinyl ester formulations in anchor bolts and chemical anchors.HPMA is particularly useful as a hydrophobic hydroxy monomer in the manufacture of sealants for vacuum impregnation of cast aluminum components. HPMA is also widely used in the production of flexible UV-curable photopolymer printing plates.

Definition

ChEBI: 2-hydroxypropyl methacrylate is an enoate ester that is the 1-methacryloyl derivative of propane-1,2-diol. It has a role as a polymerisation monomer. It is functionally related to a propane-1,2-diol and a methacrylic acid.

General Description

White liquid with a light unpleasant odor. May float or sink in water.

Reactivity Profile

2-Hydroxypropyl methacrylate polymerization: May polymerize when hot or when exposed to ultraviolet light and free-radical catalysts [USCG, 1999].

Health Hazard

Inhalation causes coughing and irritation of nose and throat; lung injury may occur. Ingestion causes irritation and burning of mouth and stomach. Contact of vapor with eyes causes irritation. Liquid may cause severe eye burns and irritation of skin.

Fire Hazard

Behavior in Fire: Compound may polymerize when hot and burst container.

Safety

2-Hydroxypropyl Methacrylate (2-HPMA) is a combustible substance. With intense healing, it forms explosive vapors with air. Vapors are heavier than air and may spread along with floors. In the case of fire, the formation of harmful gaseous products is possible. Contact with skin may cause an allergic reaction. When working with 2-Hydroxypropyl Methacrylate (2-HPMA), sanitary rules for organizing technological processes and hygienic requirements for production equipment must be strictly observed.

Properties of 2-Hydroxypropyl methacrylate

Melting point: -58°C
Boiling point: 57 °C/0.5 mmHg (lit.)
Density  1.066 g/mL at 25 °C (lit.)
vapor density  >1 (vs air)
vapor pressure  0.05 mm Hg ( 20 °C)
refractive index  n20/D 1.447(lit.)
Flash point: 206 °F
storage temp.  2-8°C
solubility  107g/l
form  Liquid
color  Clear
Specific Gravity 1.066
PH 6 (50g/l, H2O, 20℃)
Water Solubility  Soluble in water.
BRN  1752228
CAS DataBase Reference 27813-02-1(CAS DataBase Reference)
EPA Substance Registry System Hydroxypropyl methacrylate (27813-02-1)

Safety information for 2-Hydroxypropyl methacrylate

Signal word Danger
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
ghs
Health Hazard
GHS08
GHS Hazard Statements H315:Skin corrosion/irritation
H317:Sensitisation, Skin
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
H340:Germ cell mutagenicity
H350:Carcinogenicity
Precautionary Statement Codes P201:Obtain special instructions before use.
P202:Do not handle until all safety precautions have been read and understood.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P308+P313:IF exposed or concerned: Get medical advice/attention.

Computed Descriptors for 2-Hydroxypropyl methacrylate

InChIKey GNSFRPWPOGYVLO-UHFFFAOYSA-N

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