2-CHLORO-2-HYDROXYIMINOACETIC ACID ETHYL ESTER
Synonym(s):1-Ethyl oxalyl chloride 2-oxime
- CAS NO.：14337-43-0
- Empirical Formula: C4H6ClNO3
- Molecular Weight: 151.55
- MDL number: MFCD00010209
- EINECS: 604-347-4
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-06-08 17:06:38
What is 2-CHLORO-2-HYDROXYIMINOACETIC ACID ETHYL ESTER?
Chemical properties
off-white solid
The Uses of 2-CHLORO-2-HYDROXYIMINOACETIC ACID ETHYL ESTER
Ethyl 2-chloro-2-(hydroxyimino)acetate has been used:
- in the preparation of (+)-and (?)-Δ2-isoxazolines
- in the synthesis of CIP-AS (?), a chiral amino acid structurally related to glutamic acid, potential agonist at the ionotropic (±±)-2-amino-3-(3-hydroxy-5-methylisoxazol-4-yl)propionic acid (AMPA)-kainate receptors
- to generate ethoxycarbonylformonitrile oxide, in situ by treatment with sodium bicarbonate
- to prepare N-azirdinyloximes which on treatment with scandium triflate (418218) provide dihydro-oxadiazines
Properties of 2-CHLORO-2-HYDROXYIMINOACETIC ACID ETHYL ESTER
| Melting point: | 70-76 °C (lit.) |
| Boiling point: | 230.5±23.0 °C(Predicted) |
| Density | 1.36±0.1 g/cm3(Predicted) |
| storage temp. | 2-8°C |
| solubility | soluble in Methanol |
| form | powder to crystal |
| pka | 7.60±0.10(Predicted) |
| color | White to Almost white |
| Sensitive | Moisture Sensitive/Lachrymatory |
| BRN | 606193 |
| CAS DataBase Reference | 14337-43-0(CAS DataBase Reference) |
Safety information for 2-CHLORO-2-HYDROXYIMINOACETIC ACID ETHYL ESTER
| Signal word | Danger |
| Pictogram(s) |
 Corrosion Corrosives GHS05  Exclamation Mark Irritant GHS07  Health Hazard GHS08 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H318:Serious eye damage/eye irritation H334:Sensitisation, respiratory H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P280:Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P342+P311:IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician. |
Computed Descriptors for 2-CHLORO-2-HYDROXYIMINOACETIC ACID ETHYL ESTER
2-CHLORO-2-HYDROXYIMINOACETIC ACID ETHYL ESTER manufacturer
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product: 14337-43-0 Ethyl chlorooximidoacetate 98%
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