2-Bromofluorene
- CAS NO.:1133-80-8
- Empirical Formula: C13H9Br
- Molecular Weight: 245.11
- MDL number: MFCD00001115
- EINECS: 214-480-6
- SAFETY DATA SHEET (SDS)
- Update Date: 2025-01-27 09:38:02

What is 2-Bromofluorene?
Chemical properties
white to slightly yellow crystalline powder
The Uses of 2-Bromofluorene
2-Bromofluorene was used in the synthesis of end-capping reagent 2-bromo-9,9-di-nhexylfluorene. It has been used in the preparation of poly(di-n-hexylfluorene)s end capped with 2-bromofluorene, 2-bromo-9,9-di-n-hexylfluorene and 9-bromoanthracene through Ni(0) mediated polymerization. It was also used in the synthesis of 2-bromo-9,9-dihexylfluorene.
What are the applications of Application
2-Bromofluorene is a nonintrusive end-capping reagent
Synthesis Reference(s)
Journal of the American Chemical Society, 80, p. 4327, 1958 DOI: 10.1021/ja01549a053
General Description
2-Bromofluorene is a nonintrusive end-capping reagent to control molecular weights and to generate well-defined oligomers. It is used as a reagent for the preparation of dibromofluorene-labelled polystyrene by nitroxide-mediated polymerization. It is also being used in the agricultural sector as a fungicide for tomato disease control. Its carcinogenic effects on humans are currently being investigated.
Properties of 2-Bromofluorene
Melting point: | 112-114 °C (lit.) |
Boiling point: | 185 °C/135 mmHg (lit.) |
Density | 1.4187 (rough estimate) |
refractive index | 1.6290 (estimate) |
Flash point: | 185°C/135mm |
storage temp. | Sealed in dry,Room Temperature |
solubility | Soluble in chloroform and ethyl acetate. |
form | Slightly Crystalline Powder or Flakes |
color | White to slightly yellow |
BRN | 1946701 |
CAS DataBase Reference | 1133-80-8(CAS DataBase Reference) |
NIST Chemistry Reference | 9H-Fluorene, 2-bromo-(1133-80-8) |
Safety information for 2-Bromofluorene
Signal word | Warning |
Pictogram(s) |
![]() Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for 2-Bromofluorene
InChIKey | FXSCJZNMWILAJO-UHFFFAOYSA-N |
New Products
Methyl (R)-1-Boc-4,4-difluoropyrrolidine-2-carboxylate 2,2-Difluoropropylamine hydrochloride tert-butyl 3-bromoazetidine-1-carboxylate (R)-1-Boc-3-hydroxypyrrolidine DIFLUOROACETIC ANHYDRIDE 2,2-Difluoropropionic acid Diallylamine, 99% Calcium hydroxide, 95% Aluminum oxide, basic 2-Bromophenylacetonitrile, 97% L-tert-Leucine,97% N-Hydroxy-2-methylpropanimidamide 4-(3,4-Dichlorophenyl)-3,4-Dihydro-N-Methyl-1-(2H)-Naphthalenimine (Schiff Base) 2-AMINO-3,5-DIBROMO BENZALDEHYDE [ADBA] L-Glutamic Acid Dimethyl Ester Hcl 10-Methoxy-5H-dibenz[b,f]azepine 5-Cyanophthalide N, N-Carbonyldiimidazole (CDI) Dibenzoyl Peroxide Titanium Dioxide 2-(Methylthio) Benzonitrile Sodium Acetate Anhydrous Allopurinol 1,5-DibromopentaneRelated products of tetrahydrofuran







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