2-Bromofluorene
- CAS NO.:1133-80-8
- Empirical Formula: C13H9Br
- Molecular Weight: 245.11
- MDL number: MFCD00001115
- EINECS: 214-480-6
- SAFETY DATA SHEET (SDS)
- Update Date: 2025-07-24 18:13:44
What is 2-Bromofluorene?
Chemical properties
white to slightly yellow crystalline powder
The Uses of 2-Bromofluorene
2-Bromofluorene was used in the synthesis of end-capping reagent 2-bromo-9,9-di-nhexylfluorene. It has been used in the preparation of poly(di-n-hexylfluorene)s end capped with 2-bromofluorene, 2-bromo-9,9-di-n-hexylfluorene and 9-bromoanthracene through Ni(0) mediated polymerization. It was also used in the synthesis of 2-bromo-9,9-dihexylfluorene.
What are the applications of Application
2-Bromofluorene is a nonintrusive end-capping reagent
Synthesis Reference(s)
Journal of the American Chemical Society, 80, p. 4327, 1958 DOI: 10.1021/ja01549a053
General Description
2-Bromofluorene is a nonintrusive end-capping reagent to control molecular weights and to generate well-defined oligomers. It is used as a reagent for the preparation of dibromofluorene-labelled polystyrene by nitroxide-mediated polymerization. It is also being used in the agricultural sector as a fungicide for tomato disease control. Its carcinogenic effects on humans are currently being investigated.
Properties of 2-Bromofluorene
| Melting point: | 112-114 °C (lit.) |
| Boiling point: | 185 °C/135 mmHg (lit.) |
| Density | 1.4187 (rough estimate) |
| refractive index | 1.6290 (estimate) |
| Flash point: | 185°C/135mm |
| storage temp. | Sealed in dry,Room Temperature |
| solubility | Soluble in chloroform and ethyl acetate. |
| form | Slightly Crystalline Powder or Flakes |
| color | White to slightly yellow |
| BRN | 1946701 |
| CAS DataBase Reference | 1133-80-8(CAS DataBase Reference) |
| NIST Chemistry Reference | 9H-Fluorene, 2-bromo-(1133-80-8) |
Safety information for 2-Bromofluorene
| Signal word | Warning |
| Pictogram(s) |
![]() Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for 2-Bromofluorene
| InChIKey | FXSCJZNMWILAJO-UHFFFAOYSA-N |
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