2-Aminobenzyl alcohol
Synonym(s):2-(Hydroxymethyl)aniline
- CAS NO.:5344-90-1
- Empirical Formula: C7H9NO
- Molecular Weight: 123.15
- MDL number: MFCD00007749
- EINECS: 226-293-7
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-08-21 22:41:43
What is 2-Aminobenzyl alcohol?
Chemical properties
white to light yellow crystal powder.
The Uses of 2-Aminobenzyl alcohol
2-Aminobenzyl alcohol was used in the synthesis of ethyl 2-hydroxymethylcarbanilate.
What are the applications of Application
A double dehydrogenative coupling of 2-aminobenzyl alcohol with secondary aryl alcohols furnishes 2-arylquinolines in good to excellent yields under mild and sustainable conditions. The reaction is catalyzed by the molecularly defined phosphine-free nickel complex.
General Description
2-Aminobenzyl alcohol is oxidatively cyclised with an array of ketones in dioxane at 80°C in the presence of a ruthenium catalyst and KOH to give corresponding quinolines. It undergoes oxidation catalyzed by heterotrimetallic RuMnMn species on the hydrotalcite surface in the presence of O2 to yield 2-aminobenzaldehyde.
storage
Keep Cold. Air Sensitive. Light Sensitive.
Properties of 2-Aminobenzyl alcohol
Melting point: | 81-83 °C(lit.) |
Boiling point: | 162 °C15 mm Hg(lit.) |
Density | 1.0877 (rough estimate) |
refractive index | 1.4905 |
Flash point: | 160°C/10mm |
storage temp. | Keep in dark place,Inert atmosphere,Room temperature |
form | Crystalline Powder |
pka | 14.21±0.10(Predicted) |
color | Beige to gray-brown |
Water Solubility | Very soluble in water. |
BRN | 1072211 |
CAS DataBase Reference | 5344-90-1(CAS DataBase Reference) |
NIST Chemistry Reference | 2-Aminobenzyl alcohol(5344-90-1) |
EPA Substance Registry System | 2-Aminobenzenemethanol (5344-90-1) |
Safety information for 2-Aminobenzyl alcohol
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P280:Wear protective gloves/protective clothing/eye protection/face protection. P304+P340:IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P405:Store locked up. |
Computed Descriptors for 2-Aminobenzyl alcohol
InChIKey | VYFOAVADNIHPTR-UHFFFAOYSA-N |
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