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HomeProduct name list2-Aminobenzyl alcohol

2-Aminobenzyl alcohol

Synonym(s):2-(Hydroxymethyl)aniline

  • CAS NO.:5344-90-1
  • Empirical Formula: C7H9NO
  • Molecular Weight: 123.15
  • MDL number: MFCD00007749
  • EINECS: 226-293-7
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-11-21 15:02:05
2-Aminobenzyl alcohol Structural

What is 2-Aminobenzyl alcohol?

Chemical properties

white to light yellow crystal powder.

The Uses of 2-Aminobenzyl alcohol

2-Aminobenzyl alcohol was used in the synthesis of ethyl 2-hydroxymethylcarbanilate.

What are the applications of Application

A double dehydrogenative coupling of 2-aminobenzyl alcohol with secondary aryl alcohols furnishes 2-arylquinolines in good to excellent yields under mild and sustainable conditions. The reaction is catalyzed by the molecularly defined phosphine-free nickel complex.

General Description

2-Aminobenzyl alcohol is oxidatively cyclised with an array of ketones in dioxane at 80°C in the presence of a ruthenium catalyst and KOH to give corresponding quinolines. It undergoes oxidation catalyzed by heterotrimetallic RuMnMn species on the hydrotalcite surface in the presence of O2 to yield 2-aminobenzaldehyde.

storage

Keep Cold. Air Sensitive. Light Sensitive.

Properties of 2-Aminobenzyl alcohol

Melting point: 81-83 °C(lit.)
Boiling point: 162 °C15 mm Hg(lit.)
Density  1.0877 (rough estimate)
refractive index  1.4905
Flash point: 160°C/10mm
storage temp.  Keep in dark place,Inert atmosphere,Room temperature
form  Crystalline Powder
pka 14.21±0.10(Predicted)
color  Beige to gray-brown
Water Solubility  Very soluble in water.
BRN  1072211
CAS DataBase Reference 5344-90-1(CAS DataBase Reference)
NIST Chemistry Reference 2-Aminobenzyl alcohol(5344-90-1)
EPA Substance Registry System 2-Aminobenzenemethanol (5344-90-1)

Safety information for 2-Aminobenzyl alcohol

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340:IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405:Store locked up.

Computed Descriptors for 2-Aminobenzyl alcohol

InChIKey VYFOAVADNIHPTR-UHFFFAOYSA-N

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