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HomeProduct name list2-Amino-5-bromopyridine

2-Amino-5-bromopyridine

  • CAS NO.:1072-97-5
  • Empirical Formula: C5H5BrN2
  • Molecular Weight: 173.01
  • MDL number: MFCD00006323
  • EINECS: 214-019-9
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-09-04 16:41:41
2-Amino-5-bromopyridine Structural

What is 2-Amino-5-bromopyridine?

Chemical properties

Light yellow Cryst

The Uses of 2-Amino-5-bromopyridine

2-Amino-5-bromopyridine is used for the synthesis of polycyclic azaarenes.

What are the applications of Application

2-Amino-5-bromopyridine is available:
(1) Spectroscopic studies, vibrational spectroscopy, coordination and ortho analysis of 2-Amino-5-bromopyridine.
(2) As an organic synthesis reagent for the preparation of β-d-glucopyranosamine, β-d-galactopyranosamine compounds and polycyclic azulene compounds.
(3) The electrochemical reduction behaviour of 2-amino-5-bromopyridine in BMIMBF4 was investigated by cyclic voltammetry, and the reduction peak was -1.6 V (for Ag). Under the optimised conditions, 6-aminonicotinic acid was obtained in 75% yield and 100% selectivity. In addition, the ionic liquid was successfully recovered.

General Description

2-Amino-5-bromopyridine is a brominated aromatic amine reagent and is used for labeling of model reducing-end oligosaccharides via reductive amination.

Properties of 2-Amino-5-bromopyridine

Melting point: 133-138 °C (lit.)
Boiling point: 230.9±20.0 °C(Predicted)
Density  1.6065 (rough estimate)
refractive index  1.5182 (estimate)
storage temp.  Keep in dark place,Inert atmosphere,Room temperature
form  Crystalline Powder
pka 4.65±0.13(Predicted)
color  White to beige
Water Solubility  Soluble in methanol, chloroform, ethyl acetate. Slightly soluble in water.
BRN  108737
InChI InChI=1S/C5H5BrN2/c6-4-1-2-5(7)8-3-4/h1-3H,(H2,7,8)
CAS DataBase Reference 1072-97-5(CAS DataBase Reference)
EPA Substance Registry System 2-Amino-5-bromopyridine (1072-97-5)

Safety information for 2-Amino-5-bromopyridine

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P271:Use only outdoors or in a well-ventilated area.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for 2-Amino-5-bromopyridine

InChIKey WGOLHUGPTDEKCF-UHFFFAOYSA-N
SMILES C1(N)=NC=C(Br)C=C1

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