(1R,2R)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II)
Synonym(s):(R,R)-AMAC
- CAS NO.：361346-80-7
- Empirical Formula: C32H38CoN2O4
- Molecular Weight: 573.59
- MDL number: MFCD06797061
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-06-08 17:06:35
What is (1R,2R)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II)?
The Uses of (1R,2R)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II)
- Schiff base-cobalt complex catalyst for asymmetric borohydride reduction of carbonyl compounds
Catalyst for:
- Enantioselective borohydride reduction
- Stereoselective preparation of aryl alcohols via asymmetric reduction of aryl ketones with borohydride
- Stereoselective borohydride reduction of diketones to diols
- Stereoselective preparation of optically active deuterated primary alcohols via enantioselective borodeuteride reduction of aldehydes
- Stereoselective preparation of β-hydroxy esters via dynamic kinetic resolution of alkylketo esters with enantioselective borohydride reduction
- Chemoselective, diastereoselective, and enantioselective borohydride reduction of 1,3-diketones
- Asymmetric synthesis of diarylhydroxypropanones by stereoselective reduction of alkyldiaryldiketones
Properties of (1R,2R)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II)
| Melting point: | 246-250°C |
| storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
| optical activity | [α]/D 291°, c = 0.1 in chloroform |
Safety information for (1R,2R)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II)
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07  Health Hazard GHS08 |
| GHS Hazard Statements |
H302:Acute toxicity,oral H312:Acute toxicity,dermal H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H332:Acute toxicity,inhalation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation H351:Carcinogenicity |
| Precautionary Statement Codes |
P201:Obtain special instructions before use. P202:Do not handle until all safety precautions have been read and understood. P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P270:Do not eat, drink or smoke when using this product. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P308+P313:IF exposed or concerned: Get medical advice/attention. P405:Store locked up. P501:Dispose of contents/container to..… |
Computed Descriptors for (1R,2R)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II)
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