(1R)-(-)-(10-Camphorsulfonyl)oxaziridine

Synonym(s):(1R)-(−)-(Camphorylsulfonyl)oxaziridine;(1R)-(−)-2,N-Epoxy-exo-10,2-bornanesultam

CAS NO.：104372-31-8
Empirical Formula: C10H15NO3S
Molecular Weight: 229.3
MDL number: MFCD00075428
EINECS: 800-131-0
SAFETY DATA SHEET (SDS)
Update Date: 2023-08-17 18:11:45

(1R)-(-)-(10-Camphorsulfonyl)oxaziridine Structural

What is (1R)-(-)-(10-Camphorsulfonyl)oxaziridine?

Chemical properties

White crystalline powder

The Uses of (1R)-(-)-(10-Camphorsulfonyl)oxaziridine

Reactant involved in:

Asymmetric synthesis of proton pump inhibitors
Asymmetric synthesis of polyhydroxylated pyrrolidines
Diastereoselective hydroxylation of chlorophylls a and b enolate anions

Used in impregnated silica nanoparticles for removal of sulfur mustard from wastewater

Used to modify blebbistatin for investigations of myosin inhibitor design

The Uses of (1R)-(-)-(10-Camphorsulfonyl)oxaziridine

(1R)-(-)-(10-Camphorsulfonyl)oxaziridine is a useful synthetic intermediate. Used for asymmetric hydroxylation.

What are the applications of Application

(1R)-(?)-(10-Camphorsulfonyl)oxaziridine is a useful synthetic intermediate used for asymmetric hydroxylation

Properties of (1R)-(-)-(10-Camphorsulfonyl)oxaziridine

Melting point:	170-174 °C
Boiling point:	317.6±25.0 °C(Predicted)
alpha	-46.6 º (c=2, CHCl3 25 ºC)
Density	1.2486 (rough estimate)
refractive index	1.5060 (estimate)
Flash point:	170℃
storage temp.	2-8°C
solubility	Chloroform (Slightly), Methanol (Slightly)
form	Powder
pka	-11.75±0.40(Predicted)
color	White
optical activity	[α]20/D 44°, c = 2.2 in chloroform
BRN	6274369
CAS DataBase Reference	104372-31-8(CAS DataBase Reference)

Safety information for (1R)-(-)-(10-Camphorsulfonyl)oxaziridine

Signal word	Warning
Pictogram(s)	Exclamation Mark Irritant GHS07
GHS Hazard Statements	H302:Acute toxicity,oral H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes	P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P280:Wear protective gloves/protective clothing/eye protection/face protection. P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.