1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE
Synonym(s):N,N′-(2,4,6-Trimethylphenyl)dihydroimidazolium chloride;1,3-Dimesitylimidazolidinium chloride;4,5-Dihydro-1,3-bis(2,4,6-trimethylphenyl)-1H-imidazolium chloride;4,5-Dihydro-1,3-dimesityl-1H-imidazolium chloride
- CAS NO.：173035-10-4
- Empirical Formula: C21H29ClN2
- Molecular Weight: 344.92
- MDL number: MFCD09039279
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-06-19 22:55:17
What is 1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE?
Chemical properties
beige to pink-brown powder
The Uses of 1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE
N-Heterocyclic Carbene Ligands Precursor to an N-heterocyclic carbene catalysts
The Uses of 1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE
N-Heterocyclic Carbene Ligands
Precursor to an N-heterocyclic carbene catalysts used for:
- A regioselective cycloadditon of terminal acetylenes with azides leading to 1,4-disubstitutedtriazoles. Internal acetylenes can also be used with this catalyst.
- Markovnikov-type hydration of terminal alkynes
- Hydrosilylation of ketones and cycloaddition of azides and alkynes
- Suzuki-Miyaura reactions
- Luminescence experiments
General Description
1,3-Bis(2,4,6-trimethylphenyl)imidazolinium chloride is an NHC (N-heterocyclic carbene) ligand which can bind with metal pre-catalysts to form complexes that show high catalytic activity.
Properties of 1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE
| Melting point: | 280-286 °C |
| storage temp. | Inert atmosphere,Room Temperature |
| form | Powder |
| color | Beige to pink-brown |
| Sensitive | air sensitive |
| CAS DataBase Reference | 173035-10-4 |
Safety information for 1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for 1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE
| InChIKey | COGMCBFILULEOS-UHFFFAOYSA-M |
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